# Universal impurity-induced bound state in topological superfluids

###### Abstract

We predict a universal mid-gap bound state in topological superfluids, induced by either non-magnetic or magnetic impurities in the strong scattering limit. This universal state is similar to the lowest-energy Caroli-de Gennes-Martricon bound state in a vortex core, but is bound to localized impurities. We argue that the observation of such a universal bound state can be a clear signature for identifying topological superfluids. We theoretically examine our argument for a spin-orbit coupled ultracold atomic Fermi gas trapped in a two-dimensional harmonic potential, by performing extensive self-consistent calculations within the mean-field Bogoliubov-de Gennes theory. A realistic scenario for observing universal bound state in ultracold K atoms is proposed.

###### pacs:

03.75.Ss, 03.75.Hh, 05.30.Fk, 67.85.-dTopological superfluids are of great interest Qi2011 (). They are promising candidates that host Majorana fermions Majorana1937 (), which lie at the heart of topological quantum information and computation, due to their exotic non-Abelian exchange statistics Kitaev2006 (); Nayak2008 (); Wilczek2009 (). To date, there are a number of proposals for practical realizations of topological superfluids, including superconductors Read2000 (); Mizushima2008 (), surfaces of three-dimensional (3D) topological insulators Fu2008 (); Sau2010 (); Alicea2010 () or one-dimensional (1D) spin-orbit coupled nanowires Lutchyn2010 (); Oreg2010 () in proximity to an -wave superconductor, and two-dimensional (2D) Zhang2008 (); Sato2009 (); Zhu2011 (); Liu2012a () or 1D Jiang2011 (); Liu2012b (); Wei2012 () spin-orbit coupled atomic Fermi gases near Feshbach resonances. All these proposals are appealing and are to be examined experimentally. In fact, recent experimental results on tunneling spectroscopy of semiconductor InSb nanowires in a magnetic field placed in contact with a superconducting electrode Mourik2012 () may already suggest the existence of topological superfluids and Majorana fermions. However, unambiguous characterizations of topological properties of the nanowires are still missing.

In this Letter, we propose that a universal mid-gap bound state, induced by strong non-magnetic or magnetic impurity scattering, could provide a clear signature for the existence of topological superfluids. In solid state, impurities are widely known to serve as an important local probe that characterizes the quantum state of hosting systems Balatsky2006 (). Individual impurities have used to determine the superconducting pairing symmetry of unconventional non-s-wave superconductors Mackenzie1998 () and to demonstrate Friedel oscillations on Be(0001) surface Sprunger1997 (). In strongly-correlated many-body systems, they may be employed to pin one of the competing orders Millis2003 (). Here, unique to topological superfluids, we predict that a single impurity with sufficiently strong scattering strength can create a universal mid-gap state bound to the impurity. It resembles the lowest-energy Caroli-de Gennes-Martricon (CdGM) bound state inside a vortex core CdGM (). For small order parameters, where the bound state energy is nearly zero, the wave-function of the universal bound state is found to closely follow the symmetry of that of Majorana fermions Liu2012a ().

In our work, the emergence of universal impurity-induced bound state is examined theoretically in an interacting spin-orbit coupled ultracold atomic Fermi gas in 2D harmonic traps Liu2012a (). We perform numerically extensive self-consistent calculations by using fully microscopic Bogoliubov-de Gennes (BdG) theory, to explore the details of the universal bound state. This specific choice of topological superfluids is motivated by the recent realization of spin-orbit coupling in atomic Fermi gases of K exptShanXi () and Li atoms exptMIT (). Benefited from the high controllability in interaction, geometry and purity in cold-atom experiments, 2D spin-orbit coupled atomic Fermi gases are arguably the best candidate for observing the predicted universal bound state. Our results, however, should be applicable as well to various topological superfluids that are believed to exist in solid state. We propose a realistic scenario of creating universal bound state in K atoms and discuss briefly the relevance of our results to other solid state systems.

Mean-field BdG equation. — To start, we consider a trapped 2D atomic Fermi gas with a Rashba-type spin-orbit coupling and a Zeeman field , which is believed to be a topological superfluid when the Zeeman field exceeds a threshold Liu2012a (). The model Hamiltonian of the system is given by, , where

(1) |

is the single-particle Hamiltonian density in the presence of Rashba spin-orbit coupling , represents the interaction, and describes the potential scattering due to the impurity. Here, are respectively the creation field operators for the spin-up and spin-down atoms and, is the single-particle Hamiltonian in a 2D harmonic trapping potential , in reference to the chemical potential . We have used the standard -wave contact interaction between atoms with opposite spins, whose strength is to be regularized by the binding energy of the two-body bound state Liu2012a (); Randeria1989 (). For computational simplicity, we place an impurity at origin and consider either a delta-like scattering potential, , or a gaussian-shape potential with width , . In the case of magnetic impurity, we take the potential strength ; while for non-magnetic impurity, . We have checked both positive and negative values of and have observed very similar results at large . Hereafter, we focus on the case with .

We solve the low-energy fermionic quasiparticles of the model Hamiltonian by using the standard mean-field BdG approach, , where

(2) |

is the BdG Hamiltonian, and are the Nambu spinor wave-functions and energies for quasiparticles, respectively. Within mean-field, the order parameter takes the form and, is to be solved self-consistently together with the atomic densities, . Here is the Fermi distribution function at temperature . The chemical potential , implicit in , can be determined by the total number of atoms using the number equation . As the impurity is placed at origin , the BdG Hamiltonian preserves rotational symmetry. Therefore, we take and decouple the BdG equation into different angular momentum channels indexed by an integer , with which the quasiparticle wave functions become, . By expanding and in the basis of 2D harmonic oscillators, the solution of BdG equation converts to a matrix diagonalization problem. Numerically we have to truncate the summation over energy levels . This is done by introducing a high energy cut-off , above which a local density approximation is used for high-lying wave-functions Liu2007 (). We have checked that such a hybrid procedure is numerically very efficient.

For the results presented here, we have solved self-consistently the BdG equation for a cloud with atoms at zero temperature. In 2D harmonic traps, it is convenient to use the Fermi radius and Fermi energy as the units for length and energy, respectively. The strength of impurity scattering potential will be measured in units of . We have taken an interaction parameter and a spin-orbit coupling strength . With these parameters, the whole Fermi cloud becomes a topological superfluid when the Zeeman field is larger than a threshold Liu2012a (). Let us first consider the localized impurities with a delta-like scattering potential .

Emergence of universal impurity bound state. — According to Anderson’s theorem Anderson1959 (), a conventional s-wave superfluid can barely be affected by non-magnetic impurities. In contrast, magnetic impurities can break time-reversal symmetry of superfluid and act as pair breakers, leading to the appearance of mid-gap state - the so-called Yu-Shiba state - which is bound to localized impurities inside the pairing gap Yu1965 (); Shiba1968 (). The energy of such a mid-gap bound state is determined by the strength of the impurity scattering potential . As increases, the Yu-Shiba state moves from the upper gap edge to the lower gap edge for the spin-up atoms and moves oppositely for the spin-down atoms. In the presence of Rashba spin-orbit coupling, we have confirmed numerically that the above statements continue to hold, even under a Zeeman field, if the Fermi cloud is not a topological superfluid. For a typical parameter , with increasing the strength of magnetic impurity, we find that the position of the Yu-Shiba state moves very quickly from one gap edge to the other.

In contrast, once the Zeeman field is beyond the threshold so that the whole Fermi cloud becomes a topological superfluid, we observe entirely different behavior, as revealed in Fig. 1. For non-magnetic impurities, an unexpected bound state appears from one gap edge as the impurity strength is larger than a critical strength . As increases, the bound state moves towards, but never reaches zero energy. In fact, its energy saturates quickly to , where is the gap parameter at the trap center in the absence of impurity. For magnetic impurities, the dependence of the position of the Yu-Shiba state on the impurity strength is also strongly modified: at large impurity scattering, the Yu-Shiba state now moves to , nearly at the same energy as the new bound state induced by strong non-magnetic impurities. This coincidence in the energy of bound states clearly indicates that in topological superfluids a universal bound state emerges in the limit of strong impurity scattering.

Origin of the universal state. — The appearance of bound states implies that the gap parameter would be strongly depleted close to the impurity. In Fig. 2, we examine the spatial profile of order parameter near the impurity. For a weak non-magnetic impurity, as shown in Fig. 2(a), the gap parameter is already strongly modified at . Being regarded as a scattering potential for Bogoliubov quasiparticles CdGM (), the gap parameter hence starts to accommodate a bound state. For a weak magnetic impurity (Fig. 2(b)), the pair-breaking effect is always significant enough to induce a Yu-Shiba bound state, as anticipated. In the strong scattering limit, it is remarkable that the gap parameter acquires a universal spatial profile, despite the type and strength of impurities. It is fully depleted at the impurity site and has a very similar distribution as the gap parameter inside a vortex core. Therefore, we anticipate that the observed universal bound state would resemble the well-known CdGM vortex-core bound states CdGM (). Indeed, the energy of the universal impurity state, , is at the same order as that of CdGM bound states.

Now, the formation of the universal bound state can be easily understood from its analogy with the CdGM vortex-core state. As the gap parameter is fully suppressed at the impurity site, we have a local point defect (i.e., vacuum) that is topologically trivial. Due to the topological nature of the Fermi cloud away from the impurity, there would be an interface between the non-topological and topological components, which can host a gapless Majorana edge state Shen2011 (). The observed universal impurity state is precisely such a Majorana edge mode. However, its energy is not exactly zero due to the finite confinement of the system Alicea2012 (). As derived analytically by Stone and Roy Stone2004 () (see also Ref. Alicea2012 ()), the dispersion relation of edge states in topological superfluids with a confinement length is given by . By assuming a characteristic length for the gap parameter distribution CdGM (), where is the Fermi velocity, we estimate that , in good agreement with the observed energy of the universal bound state.

In Fig. 3, we examine the wave-function of the universal bound state. Indeed, it satisfies approximately the symmetry , which should be obeyed by zero-energy Majorana fermions. In the inset, we present the LDOS close to the impurity site. The universal bound state is clearly visible within the gap. Experimentally, the LDOS may be measured through spatially resolved radio–frequency (rf) spectroscopy Shin2007 (), which provides a cold-atom analog of the widely used scanning tunneling microscope in solid state OurImpurityPRA (). The wave-function of the universal bound state can therefore be determined from the real-space structure of LDOS within the gap.

Loss of university. — The universality of the impurity-induced bound state can be lost if the impurity scattering has a finite width. In this case, a hole will be created in the strong impurity scattering limit, instead of a point defect. Therefore, there are a series of edge states. The wave-function and energy of these edge states would depend critically on the shape and strength of the impurity potential. In Fig. 4, we show the bound states induced by a non-magnetic (a) and a magnetic (b) gaussian impurity, with a finite width . It is readily seen that with increasing the impurity strength the bound state never approaches to a universal limit. We have checked that for larger widths, the LDOS becomes very complicated, as more and more bound states appear.

Experimental proposal. — We now show that ultracold Fermi gases of K atoms is a potential candidate for observing the predicted universal impurity-induced bound state. A 3D spin-orbit coupled K Fermi gas was recently realized at Shanxi university exptShanXi (). By loading a pancake-like optical trap with trapping frequencies Dyke2011 () or using a deep 1D optical lattice Frohlich2011 (), a 2D topological superfluid with number of atoms and size may be prepared at the temperature about . It is convenient to create the delta-like impurity potential by using a dimple laser beam that has a sufficiently narrow beam width DimpleImpurity (), so that . By suitably tuning its frequency, the scattering potential caused by the laser beam can be attractive or repulsive for different spins. Thus, both non-magnetic and magnetic impurities can be simulated. The resulting universal bound state may be visualized by using the standard tool of spatially resolved rf-spectroscopy. All the techniques required to observe the predicted universal state are therefore within the reach of current experiments.

Application to other solid state systems. — Our results are apparently applicable to the triplet superconductor SrRuO. For the possible 1D topological superconductor reported recently in InSb nanowires Mourik2012 (), a strong impurity potential would split the 1D topological superconductor into two. Therefore, at the impurity site we anticipate two universal bound states, with precise zero-energy. The observation of such a pair of zero-energy Majorana fermions is an unambiguous identification of the topological nature of InSb nanowires.

Conclusion. — We have investigated the non-magnetic and magnetic impurity scattering in an atomic topological superfluid and have predicted the existence of universal bound state for strong impurity scatterings. The observation of such a universal bound state - via spatially resolved radio-frequency spectroscopy - is a smoking-gun proof of atomic topological superfluidity. Our prediction seems within experimental reach and opens the way to unambiguously characterizing the topological properties of other solid-state systems, such as the unconventional superconductor SrRuO and 1D topological superconductor of InSb nanowires.

Note added. — After completing this work, we were aware a related non-self-consistent T-matrix calculation in 1D topological superconductors, which predicted a bound state induced by non-magnetic impurities Sau2012 ().

###### Acknowledgements.

L.J. acknowledges stimulating discussions with Eite Tiesinga. H.H. and X.-J.L are supported by the ARC DP0984522 and DP0984637 and the NFRP-China 2011CB921502. H.P. acknowledges the support from the NSF, the Welch Foundation (Grant No. C-1669) and the DARPA OLE program. C.Y. is supported by the NSFC-China and the State Key Programs of China.## References

- (1) X.-L. Qi and S.-C. Zhang, Rev. Mod. Phys. 83, 1057 (2011).
- (2) E. Majorana, Nuovo Cimento 14, 171 (1937).
- (3) A. Kitaev, Ann. Phys. (N.Y.) 321, 2 (2006).
- (4) C. Nayak, S. Simon, A. Stern, M. Freedman, and S. Das Sarma, Rev. Mod. Phys. 80, 1083 (2008).
- (5) F. Wilczek, Nature Phys. 5, 614 (2009).
- (6) N. Read and D. Green, Phys. Rev. B 61, 10267 (2000).
- (7) T. Mizushima, M. Ichioka, and K. Machida, Phys. Rev. Lett. 101, 150409 (2008).
- (8) L. Fu and C. L. Kane, Phys. Rev. Lett. 100, 096407 (2008).
- (9) J. D. Sau, R. M. Lutchyn, S. Tewari, and S. Das Sarma, Phys. Rev. Lett. 104, 040502 (2010).
- (10) J. Alicea, Phys. Rev. B 81, 125318 (2010).
- (11) R. M. Lutchyn, J. D. Sau, and S. D. Sarma, Phys. Rev. Lett. 105, 077001 (2010).
- (12) Y. Oreg. G. Refael, and F. von Oppen, Phys. Rev. Lett. 105, 177002 (2010).
- (13) C. Zhang, S. Tewari, R. Lutchyn, and S. Das Sarma, Phys. Rev. Lett. 101, 160401 (2008).
- (14) M. Sato, Y. Takahashi, and S. Fujimoto, Phys. Rev. Lett. 103, 020401 (2009).
- (15) S.-L. Zhu, L. B. Shao, Z. D. Wang, and L. M. Duan, Phys. Rev. Lett. 106, 100404 (2011).
- (16) X.-J. Liu, L. Jiang, H. Pu, and H. Hu, Phys. Rev. A 85, 021603(R) (2012).
- (17) L. Jiang, T. Kitagawa, J. Alicea, A. R. Akhmerov, D. Pekker, G. Refael, J. I. Cirac, E. Demler, M. D. Lukin, and P. Zoller, Phys. Rev. Lett. 106, 220402 (2011).
- (18) X.-J. Liu and H. Hu, Phys. Rev. A 85, 033622 (2012).
- (19) R. Wei and E. J. Mueller, arXiv:1208.5450.
- (20) V. Mourik, K. Zuo, S. M. Frolov, S. R. Plissard, E. P. A. M. Bakkers, and L. P. Kouwenhoen, Science 336, 1003 (2012); L. P. Rokhinson, X. Liu, and J. K. Furdyna, Nature Phys. 8, 795 (2012).
- (21) A. V. Balatsky, I. Vekhter, and J.-X. Zhu, Rev. Mod. Phys. 78, 373 (2006).
- (22) E. W. Hudson, K. M. Lang, V. Madhavan, S. H. Pan, H. Eisaki, S. Uchida, and J. C. Davis, Nature (London) 411, 920 (2001).
- (23) P. T. Sprunger, L. Petersen, E. W. Plummer, E. Lægsgaard, and F. Besenbacher, Science 275, 1764 (1997).
- (24) A. J. Millis, Solid State Commun. 126, 3 (2003).
- (25) C. Caroli, P. G. de Gennes, and J. Matricon, Phys. Lett. 9, 307 (1964).
- (26) P. Wang, Z.-Q. Yu, Z. Fu, J. Miao, L. Huang, S. Chai, H. Zhai, and J. Zhang, Phys. Rev. Lett. 109, 095301 (2012).
- (27) L. W. Cheuk, A. T. Sommer, Z. Hadzibabic, T. Yefsah, W. S. Bakr, and M. W. Zwierlein, Phys. Rev. Lett. 109, 095302 (2012).
- (28) M. Randeria, J.-M. Duan, and L.-Y. Shieh, Phys. Rev. Lett. 62, 981 (1989).
- (29) X.-J. Liu, H. Hu, and P. D. Drummond, Phys. Rev. A 75, 023614 (2007).
- (30) P. W. Anderson, J. Phys. Chem. Solids, 11, 26 (1959).
- (31) L. Yu, Acta Phys. Sin. 21, 75 (1965).
- (32) H. Shiba, Prog. Theor. Phys. 40, 435 (1968).
- (33) W.-Y. Shan, J. Lu, H.-Z. Lu, and S.-Q. Shen, Phys. Rev. B 84, 035307 (2011). J. Lu, W.-Y. Shan, H.-Z. Lu, and S.-Q. Shen, New J. Phys. 13, 103016 (2011).
- (34) J. Alicea, Rep. Prog. Phys. 75, 076501 (2012).
- (35) M. Stone and R. Roy, Phys. Rev. B 69, 184511 (2004).
- (36) Y. Shin, C. H. Schunck, A. Schirotzek, and W. Ketterle, Phys. Rev. Lett. 99, 090403 (2007).
- (37) L. Jiang L. O. Baksmaty, H. Hu, Y. Chen, and H. Pu, Phys. Rev. A 83, 061604(R) (2011).
- (38) P. Dyke, E. D. Kuhnle, S. Whitlock, H. Hu, M. Mark, S. Hoinka, M. Lingham, P. Hannaford, and C. J. Vale, Phys. Rev. Lett. 106, 105304 (2011).
- (39) B. Fröhlich, M. Feld, E. Vogt, M. Koschorreck, W. Zwerger, and M. Köhl, Phys. Rev. Lett. 106, 105301 (2011).
- (40) D. M. Stamper-Kurn, H.-J. Miesner, A. P. Chikkatur, S. Inouye, J. Stenger, and W. Ketterle, Phys. Rev. Lett. 81, 2194 (1998).
- (41) J. D. Sau and E. Demler, arXiv:1204.2537.