Supremacy of the quantum many-body Szilard engine with attractive bosons
In a classic thought experiment, Szilard Szilard1929 () suggested a heat engine where a single particle, for example an atom or a molecule, is confined in a container coupled to a single heat bath. The container can be separated into two parts by a moveable wall acting as a piston. In a single cycle of the engine, work can be extracted from the information on which side of the piston the particle resides. The work output is consistent with Landauer’s principle that the erasure of one bit of information costs the entropy Landauer1961 (); Bennett1982 (); Leff2003 (), exemplifying the fundamental relation between work, heat and information Maruyama2009 (); Toyabe2010 (); Eisert2015 (); Parrondo2015 (); Lutz2015 (); Quan2007 (); Uzdin2015 (). Here we apply the concept of the Szilard engine to a fully interacting quantum many-body system. We find that a working medium of a number of bosons with attractive interactions is clearly superior to other previously discussed setups Kim2011 (); Kim2012 (); Cai2012 (); Jeon2016 (); Zhuang2014 (); Lu2012 (). In sharp contrast to the classical case, we find that the average work output increases with the particle number. The highest overshoot occurs for a small but finite temperature, showing an intricate interplay between thermal and quantum effects. We anticipate that our finding will shed new light on the role of information in controlling thermodynamic fluctuations in the deep quantum regime, which are strongly influenced by quantum correlations in interacting systems Perarnau2015 ().
The Szilard engine was originally designed as a thought experiment with only a single classical
particle Szilard1929 () to illustrate the role of information in
thermodynamics (see, for example, Parrondo2015 () for a recent review).
The apparent conflict with the second law could be resolved by
properly accounting for the work cost associated with the information
processing Landauer1961 (); Bennett1982 (); Piechocinska2000 (); Plenio2001 (); Sagawa2008 (); Sagawa2009 ().
Although Szilard’s suggestion dates back to 1929, only more recently the conversion between information and energy was shown experimentally using a Brownian particle Toyabe2010 ().
A direct realisation of the classical Szilard cycle was reported by
Roldán et al. Roldan2014 () for a colloidal particle in an optical double-well trap.
In a different scenario, Koski et
al. Koski2014 (); Koski2015 () measured of work for
one bit of information using a single electron moving between
two small metallic islands.
A quantum version of the single-particle Szilard engine was first
discussed by Zurek Zurek1986 (). In contrast to the classical
case, insertion or removal of a wall in a quantum system shifts the
energy levels, implying that the process must be associated with
non-zero work Bender2005 (); Gea2002 (); Gea2005 (). Kim et
al. Kim2011 () showed that the amount of work that can be
extracted crucially depends on the underlying quantum statistics: two
non-interacting bosons were found superior to the classical
equivalent, as well as to the corresponding fermionic case.
Many different facets of the quantum Szilard engine have been studied, including optimisation of the cycle Cai2012 (); Jeon2016 () or the effect of spin Zhuang2014 () and parity Lu2012 (), but all for non-interacting particles. The case of two attractive bosons was discussed in Ref. Kim2012 (); however, the authors assigned the increased work output to a classical effect. The question thus remains how the information-to-work conversion in many-body quantum systems is affected by interactions between the particles.
Here, we present a full quantum many-body treatment of spin-0 bosonic particles in a Szilard engine with realistic attractive interactions between the particles, as they commonly occur in, for example, ultra-cold atomic gases Bloch2008 (). We demonstrate quantum supremacy in the few-body limit for , where a solution to the full many-body problem can be obtained with very high numerical accuracy. A perturbative approach indicates that the supremacy further increases for larger particle numbers. Surprisingly, the highest overshoot of work compared to (i.e., the highest possible classical work output) occurs for a finite temperature, exemplifying the relation between thermodynamic fluctuations and the many-particle excitation spectrum.
Ii Many-body Szilard cycle for bosons with attractive interactions.
Our claim is based on a fully ab initio simulation of the quantum many-particle Szilard cycle by exact numerical diagonalisation, i.e., the full configuration interaction method (as further described in the supplementary material). A hard-walled one-dimensional container of length confines bosons that constitute the working medium. We model the interactions by the usual two-body pseudopotential of contact type Bloch2008 (), , where the strength of the interaction is given in units of . The single-particle ground state energy sets the energy unit, where is the mass of a single particle. The cycle of the Szilard engine goes through four steps, assumed to be carried out quasi-statically and in thermodynamic equilibrium with a single surrounding heat bath at temperature : (i) insertion of a wall dividing the quantum many-body system at a position , followed by (ii) a measurement of the actual particle number on the left side of the wall, (iii) reversible translation of the wall to its final position depending on the outcome of the measurement, and finally (iv) removal of the barrier at .
The total average work output of a single cycle with processes (i)-(iv) has been determined Kim2011 () as
Here, denotes the probability to find particles to the left of the wall located at position , and particles to the right, if the combined system is in thermal equilibrium. The -particle eigenstates with energy , obtained by numerical diagonalisation, can be classified by the particle number in the left subsystem with . Then we find that with .
Measuring the particle number on one side after insertion of the wall, one gains the Shannon information ShannonBellSystemTechJ1948 () Going back to the original state in the cycle, this information is lost, associated with an average increase of entropy . This increase in entropy of the system allows one to extract the average amount of work which can be positive. Here, the equality only holds if all . In this case the removal of the barrier is reversible for each observed particle number. This reversibility had been associated with the conversion of the full information gain into work Horowitz2011 (), as explicitly assumed in Ref. Plesch2014 (). While is straightforward for the single-particle case with and , this is hard to realise for Horowitz2011 ().
For our case of a moving piston, the full work can typically not be extracted. To optimise , we choose the optimal , maximising for all systems considered here. (The procedure is similar to the non-interacting case Jeon2016 ()).
The highest relative work output is obtained for a many-body system of attractive bosons at a finite temperature. This is the white region in the top panel of Fig. 1 (a), where the work output for a system of four attractive bosons surpasses the results for noninteracting (middle panel with ) as well as for repulsive (lowest panel) bosons. For comparison a system of four classical particles has (not shown here). We also note that for interaction strengths , the maximum work output always occurs if the wall is inserted in the middle of the container () for an engine operating in the deep quantum regime. (For larger temperatures, other insertion positions can become favorable, see the Supplementary Material). For , the work output vanishes if . In this limit all non-interacting bosons occupy the lowest single-particle quantum level. After insertion of the wall, the energetically lowest-lying level is in the larger region. For we know beforehand the location of the particles and measuring the number of particles does not provide any new information, i.e., . Consequently, no work can be extracted in the cycle. Attractive interactions obviously enhance this feature. However, this does not hold for repulsive interactions, , as shown in the lowest panel of Fig. 1 (a). In this case, the particles spread out on different sides of the wall in the ground state. Here, degeneracies between different many-particle states occur at particular values of , which allow an information gain in the measurement. This explains the distinct peaks as a function of for low temperature in the lowest panel of Fig. 1 (a).
The maximum of for attractive bosons increases with particle number, as shown in Fig. 1 (b). The optimal relative work output is higher for attractive bosons (solid red line) than for non-interacting bosons (red dashed line) and clearly beats the corresponding result for classical particles (blue dashed line). Here, the data for were obtained by exact diagonalisation while a perturbative approach (see supplementary material) was applied for . The peak work output for bosons with attractive interactions at a finite temperature is a general feature, which holds for a wide range of interaction strengths, see Fig. 1 (c) for the case of bosons. Indeed, the temperature at which the peak occurs increases with larger interaction strengths.
Iii Onset of the peak at an intermediate temperature.
For systems with attractive interactions, , the work output equals at low temperatures, independent of . Due to the dominance of the attractive interaction, all particles will be found on one side of the barrier. When the barrier is inserted symmetrically, we have , while all other . At the same time, the removal position and provide and , so that Eq. (1) provides the work output for the entire cycle as observed in Fig. 1(c). This case, with two possible measurement outcomes and a full sweep of the piston, resembles the single-particle case. One might wonder, whether the increased particle number should not imply a higher pressure on the piston and thus, more work. This, however, is not the case, as the attraction between the particles reduces the pressure. Also, when inserting the barrier, the difference in work due to the interactions has to be taken into account. With increasing temperature (i.e., , for weak interactions as shown in the supplementary material) other measurement outcomes than or become probable. Since and now decrease with temperature we see a deviation from the performance of the single-particle engine.
Iv The two-particle interacting engine.
To get a better understanding of the physics behind the enhancement of work output for bosons with attractive interactions at finite temperatures, let us look at the two-particle case in some more detail. For a central insertion of the barrier, we find . For the same symmetry reasons, has a maximum at this barrier position. No work can thus be extracted in cycles where the two particles are measured on different sides of the central barrier, since in Eq. (1).
Thus, the only contributions to the work output result from and . Together with we obtain
This function has its peak at with the peak value , see Fig. 2. This implies a finite value . Even if no work can be extracted with one particle on either side of the barrier, a non-zero probability of such a measurement outcome can be preferable.
Two attractive bosons, initially at and with , will for increasing continuously approach the classical limit of . Hence, at a certain temperature, depending on the interaction strength, passes through producing a peak in the relative work. Physically, one may understand this property of the engine as follows: At low temperatures, the two attractive bosons will always end up on the same side of the barrier, bound together by their attraction. The cycle is then operating similar to the single particle case, which explains that when . A less correlated system (obtained with increasing ) provides a larger expansion work for cycles in which both particles are on one side of the barrier. On the other hand, cycles with one particle on each side of the barrier, from which no work can be extracted, become more frequent. For , the enhanced pressure is more important and the average work output increases with decreasing . For lower values of , i.e. , too few cycles contribute on average to the work production. The average work output decreases with decreasing despite the corresponding increase in pressure. Importantly, we note the absence of a similar maximum in the non-interacting case, where is found to decrease steadily towards the classical limit with increasing .
V Szilard engines with attractive bosons.
The maximum of tends to increase with the particle number (as previously discussed in connection with Fig. 1 b). The reason lies in the fact that work can be extracted from a larger number of measurement outcomes. Similar to the two-particle engine, the combined contribution to the average work output from cycles in which all particles are on the same side of a barrier inserted at is given by Eq. (2). However, also cycles with (except if ) on the left side of the barrier do contribute to the average work output, and work output even higher than in the two-particle case is possible. The maximum of and that of occurs for , as clearly indicated by the probabilities for different measurement outcomes shown for in Fig. 3. This means that is possible for and that work may be extracted in agreement with Eq. (1). For all systems considered here, with insertion of the barrier at the midpoint the optimum is reached for (see the example for in Fig. 3), which is close to the optimal value of for the corresponding two-particle engine.
Vi Repulsive Bosons
Finally, we consider the repulsive interactions between bosons, see Figure 1(c). In the low-temperature limit, the relative work output is very similar to that of non-interacting spin-less fermions discussed in Refs. Kim2012 (); Cai2012 (). This resemblance becomes even more pronounced with increasing interaction strength. This in fact is no coincidence, but rather a property of one-dimensional bosons with strong, repulsive interactions that have an impenetrable core: Indeed, in the limit of infinite repulsion, bosons act like spin-polarised non-interacting fermions. This is the well-known Tonks-Giradeau regime Girardeau1960 (). Both for non-interacting fermions and strongly repulsive bosons, the region where the quantum Szilard engine exceeds the classical single-particle maximum of work output, has disappeared.
We have demonstrated that the work output of the quantum Szilard engine can be significantly boosted by short-ranged attractive interactions for a bosonic working medium. We based our claim on the (numerically) exact solution of the full many-body Schrödinger equation for up to five bosons. It is likely that the effect is even further enhanced for larger particle numbers; however, despite the simple one-dimensional setup, the numerical effort grows very significantly (and beyond our feasibility) for larger . By increasing the strength of the interparticle attraction, the engine’s work output can be increased significantly also at higher temperatures, where the work that can be extracted generally is of larger magnitude. While we here restrict our analysis to idealised quasi-static processes, it would be of much interest to consider a finite speed in the ramping of the barrier, enabling transitions to excited states which by coupling to baths will lead to dissipation. Extending our approach to quantify irreversibility in real processes on the basis of a fully ab initio quantum description may in the future allow to study dissipative aspects in the kinetics of the conversion between information and work.
- (1) Szilard, L. Über die entropieverminderung in einem thermodynamischen system bei eingriffen intelligenter wesen. Z. Phys. 53, 840–856 (1929).
- (2) Landauer, R. Irreversibility and heat generation in the computing process. IBM J. Res. Dev. 5, 183–191 (1961).
- (3) Bennett, C. H. The thermodynamics of computation—a review. International Journal of Theoretical Physics 21, 905–940 (1982).
- (4) Leff, H. S. & Rex, A. F. Maxwell’s Demon 2: Entropy, Classical and Quantum Information Computing (IOP Publishing, Bristol, 2003).
- (5) Maruyama, K., Nori, F. & Vedral, V. Colloquium : The physics of Maxwell’s demon and information. Rev. Mod. Phys. 81, 1–23 (2009).
- (6) Toyabe, S., Sagawa, T., Ueda, M., Muneyuki, E. & Sano, M. Experimental demonstration of information-to-energy conversion and validation of the generalized jarzynski equality. Nature Physics 6, 988–992 (2010).
- (7) Eisert, J., Friesdorf, M. & Gogolin, C. Quantum many-body systems out of equilibrium. Nat Phys 11, 124–130 (2015).
- (8) Parrondo, J. M. R., Horowitz, J. M. & Sagawa, T. Thermodynamics of information. Nat Phys 11, 131–139 (2015).
- (9) Lutz, E. & Ciliberto, S. Information: From maxwellâs demon to landauerâs eraser. Physics Today 58, 30 (2015).
- (10) Quan, H. T., Liu, Y.-x., Sun, C. P. & Nori, F. Quantum thermodynamic cycles and quantum heat engines. Phys. Rev. E 76, 031105 (2007).
- (11) Uzdin, R., Levy, A. & Kosloff, R. Equivalence of quantum heat machines, and quantum-thermodynamic signatures. Phys. Rev. X 5, 031044 (2015).
- (12) Kim, S. W., Sagawa, T., De Liberato, S. & Ueda, M. Quantum Szilard engine. Phys. Rev. Lett. 106, 070401 (2011).
- (13) Kim, K.-H. & Kim, S. W. Szilard’s information heat engines in the deep quantum regime. J. Korean Phys. Soc. 61, 1187–1193 (2012).
- (14) Cai, C. Y., Dong, H. & Sun, C. P. Multiparticle quantum szilard engine with optimal cycles assisted by a maxwell’s demon. Phys. Rev. E 85, 031114 (2012).
- (15) Jeon, H. J. & Kim, S. W. Optimal work of the quantum szilard engine under isothermal processes with inevitable irreversibility. New J. Phys. 18, 043002 (2016).
- (16) Zhuang, Z. & Liang, S.-D. Quantum szilard engines with arbitrary spin. Phys. Rev. E 90, 052117 (2014).
- (17) Lu, Y. & Long, G. L. Parity effect and phase transitions in quantum szilard engines. Phys. Rev. E 85, 011125 (2012).
- (18) Perarnau-Llobet, M. et al. Extractable work from correlations. Phys. Rev. X 5, 041011 (2015).
- (19) Piechocinska, B. Information erasure. Phys. Rev. A 61, 062314 (2000).
- (20) Plenio, M. & Vitelli, V. The physics of forgetting: Landauers erasure principle and information theory. Contemp. Phys. 42, 25–60 (2001).
- (21) Sagawa, T. & Ueda, M. Second law of thermodynamics with discrete quantum feedback control. Phys. Rev. Lett. 100, 080403 (2008).
- (22) Sagawa, T. & Ueda, M. Minimal energy cost for thermodynamic information processing: Measurement and information erasure. Phys. Rev. Lett. 102, 250602 (2009).
- (23) Roldan, E., Martinez, I. A., Parrondo, J. M. R. & Petrov, D. Universal features in the energetics of symmetry breaking. Nat Phys 10, 457–461 (2014).
- (24) Koski, J. V., Maisi, V. F., Pekola, J. P. & Averin, D. V. Experimental realization of a szilard engine with a single electron. Proc. Natl. Acad. Sci. 111, 13786–13789 (2014).
- (25) Koski, J. V., Kutvonen, A., Khaymovich, I. M., Ala-Nissila, T. & Pekola, J. P. On-chip maxwell’s demon as an information-powered refrigerator. Phys. Rev. Lett. 115, 260602 (2015).
- (26) Zurek, W. H. Maxwell’s demon, Szilard’s engine and quantum measurements. In Moore, G. T. & Scully, M. O. (eds.) Frontiers of Nonequilibrium Statistical Physics, 151–161 (Springer US, Boston, MA, 1986).
- (27) Bender, C. M., Brody, D. C. & Meister, B. J. Unusual quantum states: non–locality, entropy, maxwell’s demon and fractals. Proc. R. Soc. London A: Mathematical, Physical and Engineering Sciences 461, 733–753 (2005).
- (28) Gea-Banacloche, J. Splitting the wave function of a particle in a box. Am. J. Phys. 70, 307–312 (2002).
- (29) Gea-Banacloche, J. & Leff, H. S. Quantum version of the szilard one-atom engine and the cost of raising energy barriers. Fluctuation and Noise Letters 05, C39–C47 (2005).
- (30) Bloch, I., Dalibard, J. & Zwerger, W. Many-body physics with ultracold gases. Rev. Mod. Phys. 80, 885–964 (2008).
- (31) Shannon, C. E. A mathematical theory of communication. Bell Syst. Tech. J. 27, 379–423 (1948).
- (32) Horowitz, J. M. & Parrondo, J. M. R. Designing optimal discrete-feedback thermodynamic engines. New J. Phys. 13, 123019 (2011).
- (33) Plesch, M., Dahlsten, O., Goold, J. & Vedral, V. Maxwell’s daemon: Information versus particle statistics. Sci. Rep. 4, 6995 EP – (2014).
- (34) Girardeau, M. Relationship between systems of impenetrable bosons and fermions in one dimension. J. Math. Phys. 1, 516–523 (1960).
- (35) De Boor, C. A practical guide to splines; rev. ed. Applied mathematical sciences (Springer, Berlin, 2001).
- (36) Guggenheimer, J. & Holmes, P. J. Nonlinear Oscillations, Dynamical Systems, and Bifurcations of Vector Fields (Springer, Berlin, 1983).
1. Work output of the quantum Szilard engine
In contrast to other conventional heat engines that operate by exploiting a temperature gradient, as discussed in many textbooks on thermodynamics, the Szilard engine Szilard1929 () allows for work to be extracted also when connected to a single heat bath at constant temperature. It is propelled by the information obtained about the working medium and its microscopical properties. In the supplementary material, we briefly outline the theoretical description of the quantum Szilard engine, in close analogy to that of Refs. Kim2011 (); Jeon2016 (). An idealised version of the Szilard engine cycle consists of four well-defined steps: (i) insertion, (ii) measurement, (iii) expansion and finally (iv) removal. First, an impenetrable barrier is introduced (i) that effectively splits the working medium into two halves. Then, the number of particles on each side of the barrier is measured (ii). Depending on the outcome of this measurement, the barrier moves (iii) to a new position and contraction-expansion work can be extracted in the process. Finally, the barrier is removed (iv) which completes a single cycle of the engine.
All four steps, (i)-(iv), of the Szilard engine are assumed to be carried out quasi-statically and in thermodynamic equilibrium with a surrounding heat bath at temperature . Now, the work associated with an isothermal process can be obtained from
where , and are the Boltzmann constant, the Helmholtz free energy and the partition function
where the sum runs over the energies of, in principle, all micro (or quantum) states of the considered system. In practice, however, we construct an approximate partition function from a finite number of energy states. Note that the work in Eq. (3) is chosen to be positive if done by the system. Also, the equivalence between and is reserved for reversible processes alone.
We now turn to the work associated with the individual steps of the quantum Szilard engine. For simplicity, we consider an engine with particles initially confined in a one-dimensional box of size . All steps of the engine are, as previously mentioned, carried out quasi-statically and in thermal equilibrium with the surrounding heat bath at temperature . To maximise the work output, we further assume that all involved processes are reversible, unless specified otherwise.
(i) Insertion. A wall is slowly introduced at , where . In the end, the initial system is divided into left and right sub-systems of sizes and respectively. Based on Eq. (3), the work of this process is given by
where is the short-hand notation for the partition function obtained with particles in the left sub-system and in the right one. With this notation, is thus equivalent to the partition function of the initial system, before the insertion of the barrier. Also, note that prior to measurement, the number of particles on either side of the barrier is not yet a characteristic property of the new system. We need thus to sum over all possible particle numbers in the numerator of Eq. (5). Finally, we want to stress the fact that, unlike for a classical description of the engine, the insertion of a barrier costs energy in the form of work, due to the associated change in the potential landscape.
(ii) Measurement. The number of particles located on the different sides of the barrier is now measured. Here, following Kim2012 (), we assume that the measurement process itself costs no work, i.e., we assume that (see main text). The probability that particles are measured to be on the left side of the barrier (and on the right side) is given by
(iii) Expansion. The barrier introduced in (i) is assumed to move without friction. During this expansion/contraction process, the number of particles on either side of the barrier remains fixed. In other words, the barrier is assumed high enough such that tunnelling may be neglected. If the barrier moves from to when particles are measured in the left sub-system, the average work extracted from this step of the cycle reads
where are the probabilities given by Eq. (6).
(iv) Removal. The barrier at , that separates the left sub-system with particles from the right one with particles, is now slowly removed. As the height of the barrier shrinks, particles will eventually start to tunnel between the two sub-systems. This transfer of particles makes the removal of the barrier an irreversible process. Clearly, if we instead were to start without a barrier and introduce one at , then we can generally not be certain to end up with particles to the left of the partitioner. Assuming that the particles are fully delocalised between the two sub-systems already in the infinite height barrier limit, then the average work associated with the removal process is given by
Finally, the averaged combined work output of a single Szilard cycle, , is given by the sum of the partial works associated with the four steps (i)-(iv), i.e. , and simplifies into
which is the central equation (1) in the main article.
2. The interacting many-body Hamiltonian and exact diagonalisation
To keep the schematic setup of the many-body Szilard cycle as simple as possible, we consider a quantum system of interacting particles, initially confined in a one-dimensional box of size that is separated by a barrier inserted at a certain position . We note that for contact interactions between the particles, as defined in the main text, the exact energies to the fully interacting many-body Hamiltonian are those given in terms of two independent systems with and particles. In order to construct the partition functions and compute the probabilities , the entire exact many-body energy spectrum is needed. For the simple case of non-interacting particles (or single-particle systems) these energies are known analytically. For interacting particles, however, they must be determined by solving the full many-body problem. We here apply the configuration interaction method where we use a basis of the 5th order B-splines deBoor2001 (), with a linear distribution of knot-points within each left/right sub-system, to determine the energies of each sub-system and parity at each stage. For , we used 62 B-splines (or one-body states) to construct the many-body basis for each sub-system. Since the dimension of the many-body problem grows drastically with , we needed to decrease the number of B-splines to 32 for . Consequently, in this case we could not go to equally high temperatures and interaction strengths.
3. Perturbative approach for weakly attractive bosons at low temperatures
Here we consider the case , so that only the lowest quantum levels in each part are thermally occupied. In the case of vanishing interaction, the state with particles in the lowest level of the left part of the wall positioned at (and particles in the lowest level of the right part) has the energy
Applying the wave function for the left side, the mutual interaction energy between two particles in this level is
Now we assume that this interaction energy (times the number of interacting partners) is much smaller than the level spacing, i.e. , which is satisfied for . Then we may determine the energy of the many-particle state by first-order perturbation theory. This results in the interaction energy
Setting , we obtain an analytical
expression for the probabilities without any need for numerical
determining the optimal removal positions numerically,
we get the work output by Eq. (1). Again the optimal
temperature needs to be chosen to obtain the results plotted in
4. Estimate of the peak temperature
For the symmetric wall position, the ground state of the system with attractive bosons has all particles on one side, say the left one. Using the perturbative approach discussed above, the interaction energy is . If one boson is transferred from the left side to the right side, the interaction energy changes to , while the level energies are independent on for the symmetric wall position. Thus thermal excitations become likely for . For these temperatures the particles do not cluster on the same side of the wall any longer and we have .
5. Temperature dependence of the work output for different interaction strengths
As a complement to Fig. 1(c) of the main article, we show the case for here in Fig. 4. For small to medium couplings , the peaks have approximately the same height and they are shifted proportionally to . This shift follows the deviations from the low temperature limit , which set in at , as shown by the approximative approach in the main article. As discussed in the method section, for , correlation effects become important and we find a reduced peak at , similar to the case for in Fig. 1(c) of the main article. Due to the high numerical demand on the numerical diagonalization, we did not obtain results for larger in the case , while for an increase of the peak height for even larger is observed.
For all interaction strengths , the peak height is actually larger than the peak for the attractive two-particle case depicted in Fig. 2 of the main article. This is due to the fact, that Eq. (2) of the main article is a lower bound for the work output and necessarily moves from at to the classical result at large temperatures. Thus the maximum for is taken at some intermediate temperature.
6. Operation of the Quantum Szilard engine at high temperatures
For particles, Fig. 5 shows that the symmetric insertion point is not optimal for high temperatures. For classical particles, the optimal work output is given by
A numerical scan of different insertion positions shows that an asymmetric insertion point (as shown by the blue dashed line in Fig. 5) provides the highest work output. In contrast, the symmetric position is optimal for classical particles. For the non-repulsively interacting bosons () studied here, the symmetric insertion is favorable in the low temperature limit as thoroughly discussed in the main article. On the other hand, for large temperatures the classical result needs to be recovered. This occurs via a pitchfork bifurcationGuckenheimerBook1983 () at an intermediate temperature as shown in Fig. 5. For noninteracting Bosons it occurs at for , and at slightly larger values if attractive interactions are included.