# Metallic proximity effect in ballistic graphene with resonant scatterers

## Abstract

We study the effect of resonant scatterers on the local density of states in a rectangular graphene setup with metallic leads. We find that the density of states in a vicinity of the Dirac point acquires a strong position dependence due to both metallic proximity effect and impurity scattering. This effect may prevent uniform gating of weakly-doped samples. We also demonstrate that even a single-atom impurity may essentially alter electronic states at low-doping on distances of the order of the sample size from the impurity.

###### pacs:

73.63.-b, 73.22.-f, 73.23.Ad## 1 Introduction

Since the discovery of graphene [1, 2] a great progress has been made in production of high quality samples with nearly ballistic behavior of Dirac electrons [3, 4, 5]. Even though the experimental results agree well with the ballistic theory of transport [6, 7], the role of metallic contacts in electronic properties of sub-micron graphene samples is debated [8]. In this paper we introduce a notion of metallic proximity effect in graphene and show that this effect can lead to a non-uniform gating of small graphene flakes.

Despite the intense graphene studies, the scattering mechanisms, which limit electron mobility in the best available graphene flakes, are not clearly identified [9]. Still, the experimental evidence that strong impurities, such as adatoms and vacancies, dominate the scattering at low temperatures is currently building up [10, 11, 12, 13]. We demonstrate below that even the point-like impurities may introduce large spacial variations of electronic density at distances of the order of the system size from the impurity provided the quasiparticle energies are close to the Dirac degeneracy point.

An impurity can be characterized by at least two length scales: its physical size and the characteristic scattering length . The latter is determined by the scattering cross-section and, therefore, depends on the energy of Dirac quasiparticles that scatter on the impurity. A single weak impurity, i.e. the impurity with , has practically no effect on transport and electronic density of states in ballistic sample. The effect becomes essential only for a substantial concentration of weak impurities [16, 17, 18]. In contrast, a single strong impurity, i.e. the one with , can have a noticeable effect on transport [15].

The strong impurities are of a particular importance at zero doping, i.e. in the situation when the chemical potential in graphene is tuned precisely to the Dirac point. It is theoretically predicted that each strong impurity can form a resonant “mid-gap” state [14], which contributes a universal value to the conductance and shot noise [15] provided the wave-length of the Dirac quasiparticle, , exceeds the distance between the metallic leads, . The resonant conditions are equivalent to the limit . Evidently, in this regime, the properties of graphene flakes are strongly influenced by both the impurities and the sample boundaries.

The values of conductance and shot noise observed in experiments with sub-micron graphene flakes [4, 5] agree with the predictions of ballistic theory [6, 7] for , which makes us to believe that this limit is experimentally achievable. Both the ballistic theory of ref. [7] and experiment [4, 5] deal with rectangular graphene samples with large aspect ratio, , where is the sample width and is the distance between the metallic leads.

For the proximity to metal gives rise to the so-called pseudo-diffusive charge transport [19] in the model with abrupt boundary conditions at graphene-metal boundaries. We shall demonstrate below that in this model the local density of states (LDOS) takes on the most simple form, , which corresponds to the lowest curve in figure 1. The enhancement of the density near the graphene-metal interfaces illustrates the metallic proximity effect. The LDOS in the presence of a single impurity is shown in figure 2 with a contour plot for resonance and off-resonance conditions. Such a strong spacial dependence of the LDOS suggests that, in the presence of electron-electron interactions, the sample is not uniformly charged by the gate electrode.

## 2 Clean sample

The LDOS is defined by the general formula, , where the retarded Green’s function yields the matrix equation

(1) |

with . In this paper the Dirac Hamiltonian of ideal graphene, , is taken in the valley symmetric representation, where m/s is an effective ”speed of light”. The impurity potential, , is considered to be a scalar in the Dirac equation, which assumes that the corresponding physical potential is smooth on the scale of the graphene lattice. The vector is a two-component vector of Pauli matrices and the energy, , determines the wave-length of free Dirac quasiparticle as .

Following earlier works we describe the metal-graphene interfaces at with a step function model

(2) |

where is regarded as the Fermi wave length in the metallic lead. We naturally assume that . In order to avoid a detailed discussion of the sample edges we impose periodic boundary conditions in direction.

We start with a solution of equation (1) in the absence of impurity potential. This solution is most easily obtained in the channel representation, which is defined by the Fourier transform,

(3) |

where the summation runs over the discrete values of transversal momentum, . Selecting the solutions which decay in the leads we obtain the effective boundary conditions on graphene-metal interfaces in the limit [15],

(4) |

Using these boundary conditions the Green’s function inside the clean sample is readily found as

(5) |

where , and

(6) | |||

(7) |

In equation (5) the following definitions were used,

(8) | |||||

(9) |

where . The quantity, , introduced in equation (6) has a meaning of component of the quasiparticle momentum, which can take on complex values.

Thus, the LDOS of a clean system is given by the expression

(10) |

where the factor takes into account the spin and valley degeneracies. The LDOS of the clean setup has no dependence on due to the translational symmetry of the system in this direction. The -dependence of the LDOS is plotted in figure 1 for and several values of energy.

The expression (10) can be approximated in the doped graphene, , by averaging over the Friedel oscillations on the scale . Away from the boundaries, , the evanescent modes, which are characterized by complex momenta , can be disregarded and the averaging over the Friedel oscillations can be replaced by the averaging over the phase . For , the averaged LDOS value is given by , which is shown in figure 1 with dotted lines. Near the sample edge, , the density is dominated by the metallic proximity effect, so that it diverges at the metal-graphene interfaces in the limit . For and , the LDOS does not depend on energy and can be approximated as .

In contrast, for , the LDOS is fully determined by the evanescent modes. In particular, for (), the result can be obtained by taking , , and in equation (10), which leads to the expression

(11) |

In the limit , the sum over the transversal momenta, , can be replaced by the integration, with the result

(12) |

where the small term in the denominator is effective only at the edges, and , in which case the sum (11) equals the number of channels in the lead.

The result (12) shows that the LDOS at is dominated, in the limit , by the states originating in the leads. These boundary states, which are also referred to as the evanescent modes, are responsible for the so-called pseudo-diffusive transport regime in this setup [19], which is characterized by universal full counting statistics [15]. We see, therefore, that the strong metallic proximity effect is the natural property of the abrupt interface model (2), which is compatible with the transport measurements of ref. [5].

## 3 Effect of impurity

In this Section we consider the effect of a scalar point-like impurity on the LDOS at for a rectangular graphene sample with . The calculation of the Green’s function is analogous to the one presented in ref. [15] for the charge transport and can be carried out straightforwardly.

We shall start with the real space representation of the free Green’s function (5) at , that reduces, in the limit , to [15]

(13) |

where

(14) |

One can see from the equations (13,14) that the free Green’s function obeys the chiral symmetry

(15) |

which is, therefore, preserved in the abrupt interface model described by equation (2).

One can also see from equation (13) that the Green’s function at the coinciding arguments can be decomposed into the sum of the free Green’s function in an infinite system, , and the proximity-induced part, , such that

(16) |

where is off-diagonal and singular,

(17) |

while is proportional to the product of the LDOS (12) and the unit matrix,

(18) |

In order to simplify the calculation we choose the impurity potential in the form of a disk with sharp boundaries, , where the theta function, , equals for and zero otherwise. We also take the limit of point-like impurity, . In this limit the full T-matrix of the impurity can be written, in the symbolic notations, as

(19) |

where we used the decomposition (16) and introduced the reduced T-matrix, , which is represented, in the detailed notations, by the infinite sum

(20) |

The reduced T-matrix given by equation (20) does not contain any information on the metallic leads and sample boundaries. Therefore, it can be obtained from the consideration of scattering of free Dirac quasiparticles on a single disk impurity. This problem has been addressed by several authors [20, 21, 15]. The result in the s-wave approximation and in the limit takes the form

(21) |

where is the Bessel function and the T-matrix, , is proportional to the unit matrix in spin, valley, and sublattice space.

The equation (21) completes the calculation of the Green’s function in the presence of a single impurity,

(22) |

where specifies the impurity location. We stress that the characteristic impurity size, , determined by the reduced T-matrix, strongly depends on the impurity potential, , and diverges at the resonance.

From equation (22) we find the LDOS at the point , which can be written as

(23) |

This result is plotted in the figure 2 for an impurity placed in the middle of the sample, .

For the resonant conditions, , (i.e. for ) the disk impurity supports a quasi-bound state at [22, 15] with only one pseudo-spin component being localized. In this case, the LDOS is strongly enhanced at distances of the order of from the impurity. Away from the resonant condition, the effect of a single impurity on the LDOS is predictably small. It was argued on the basis of the DFT analysis [14] that some single-atom impurities such as hydrogen naturally create the mid-gap quasi-bound states. The resonance condition for such scatterers are always fulfilled near the Dirac point. Therefore, even few impurities in the sample will have a great impact on the LDOS. We expect that this effect can be observed with the STM measurements.

Finally we note that the denominator in the second term of equation (23) coincides with the denominator in the impurity contribution to the conductance in the same setup [15]. Near the resonance, the second term in equation (23) has a Lorentzian dependence on the position of the impurity level with respect to the Dirac point. This characteristic dependence reflects the resonant nature of charge transport that originates in the impurity assisted tunneling in undoped graphene [23].

## 4 Discussion

We found from equation (10) that the LDOS in ballistic rectangular sample with can be approximated as

(24) |

where is the distance to the closest graphene-metal interface. This result shows that the metal proximity effect is fully dominating the LDOS for energies close to the Dirac point, . It also demonstrates that the LDOS is never vanishing in graphene with metal boundaries.

From equation (24) we readily estimate the integrated density of states as

(25) |

where . Thus, for , the integrated density increases logarithmically with the system size, , due to the electronic states at the metal-graphene interfaces. Peculiar transport properties of ballistic graphene [19, 15] are originating in the metallic proximity effect.

Similarly, the presence of the resonant impurity has a great effect on the LDOS near the Dirac point since the corresponding electronic states localize not only on the metal interfaces but also on the impurity. This effect leads to a highly inhomogeneous electronic density profile for , which is illustrated in figure 2.

This result implies that electron-electron interactions may prevent the uniform gating of the sample in the vicinity of the Dirac point. Assuming that the interaction potential is given by we can estimate, up to a constant value, an additional potential profile in the single-electron problem (1) as

(26) |

where is the Fermi distribution function. Since only the spatially varying part of the potential is relevant, we can let . Finally the LDOS and the potential profile, , have to be found self-consistently from equation (1) with and equation (26). The detailed analysis of the non-uniform gating is, however, beyond the scope of the present paper.

## Acknowledgements

The work was supported by the DFG – Center for Functional Nanostructures and by EUROHORCS/ESF EURYI Award (I.V.G.). The discussions with Alexander Mirlin, Pablo San-Jose, Henning Schomerus, and Alexander Schuessler are gratefully acknowledged.

### References

- K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, Science 306, 666 (2004).
- K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, M. I. Katsnelson, I. V. Grigorieva, S. V. Dubonos, and A. A. Firsov, Nature (London) 438, 197 (2005).
- H. B. Heersche, P. Jarillo-Herrero, J. B. Oostinga, L. M. K. Vandersypen, and A. F. Morpurgo, Nature 446, 56 (2007).
- F. Miao, S. Wijeratne, U. Coskun, Y. Zhang, and C. N. Lau, Science 317, 1530 (2007).
- R. Danneau, F. Wu, M. F. Craciun, S. Russo, M. Y. Tomi, J. Salmilehto, A. F. Morpurgo, and P. J. Hakonen, Phys. Rev. Lett. 100, 196802 (2008).
- M. I. Katsnelson, Eur. Phys. J. B 51, 157 (2006).
- J. Tworzydło, B. Trauzettel, M. Titov, A. Rycerz, and C. W. J. Beenakker, Phys. Rev. Lett. 96, 246802 (2006).
- P. Blake, R. Yang, S. V. Morozov, F. Schedin, L. A. Ponomarenko, A. A. Zhukov, I. V. Grigorieva, K. S. Novoselov, and A. K. Geim, Solid State Commun 149, 1068-1071 (2009)
- L. A. Ponomarenko, R. Yang, T. M. Mohiuddin, S. M. Morozov, A. A. Zhukov, F. Schedin, E. W. Hill, K. S. Novoselov, M. I. Katsnelson, and A. K Geim, Phys. Rev. Lett. 102, 206603 (2009).
- F. Schedin, A. K. Geim, S. V. Morozov, D. Jiang, E. H. Hill, P. Blake, and K. S. Novoselov, Nature Materials 6, 652 (2007).
- J.-H. Chen, C. Jang, S. Adam, M. S. Fuhrer, E. D. Williams, and M. Ishigami, Nature Physics 4, 377 (2008).
- S. Y. Zhou, D. A. Siegel, A. V. Fedorov, and A. Lanzara, Phys. Rev. Lett. 101, 086402 (2008).
- D. C. Elias, R. R. Nair, T. M. G. Mohiuddin, S. V. Morozov, P. Blake, M. P. Halsall, A. C. Ferrari, D. W. Boukhvalov, M. I. Katsnelson, A. K. Geim, and K. S. Novoselov, Science 323, 610 (2009).
- T. O. Wehling, A. V. Balatsky, M. I. Katsnelson, A. I. Lichtenstein, K. Scharnberg, and R. Wiesendanger, Phys. Rev. B 75, 125425 (2007).
- M. Titov, P. M. Ostrovsky, I. V. Gornyi, A. Schuessler, and A. D. Mirlin, arXiv:0908.3793 (2009).
- P. M. Ostrovsky, I. V. Gornyi, and A. D. Mirlin, Phys. Rev. B 74, 235443 (2006).
- P. M. Ostrovsky, I. V. Gornyi, and A. D. Mirlin, Phys. Rev. Lett. 98, 256801 (2007); Eur. Phys. J. Spec. Top. 148, 63 (2007).
- A. Schuessler, P. M. Ostrovsky, I. V. Gornyi, and A. D. Mirlin, Phys. Rev. B 79, 075405 (2009).
- C. W. J. Beenakker, Rev. Mod. Phys. 80, 1337 (2008).
- M. Hentschel and F. Guinea, Phys. Rev. B 76, 115407 (2007).
- D. M. Basko, Phys. Rev. B 78, 115432 (2008).
- J. Bardarson, M. Titov, and P. W. Brouwer, Phys. Rev. Lett. 102, 226803 (2009).
- M. Titov, Europhys. Lett. 79, 17004 (2007).