Parafermions in an interacting quantum spin Hall Josephson junction coupled to an impurity spin
Abstract
parafermions can be realized in a strongly interacting quantum spin Hall Josephson junction or in a spin Hall Josephson junction strongly coupled to an impurity spin. In this paper we study a system that has both features, but with weak (repulsive) interactions and a weakly coupled spin. We show that for a strongly anisotropic exchange interaction, at low temperatures the system enters a strong coupling limit in which it hosts two parafermions, characterizing a fourfold degeneracy of the ground state. We construct the parafermion operators explicitly, and show that they facilitate fractional charge tunneling across the junction. The dependence of the effective lowenergy spectrum on the superconducting phase difference reveals an periodicity of the supercurrent.
I Introduction
The search for electronic systems that host exotic Majorana and parafermion quasiparticles has attracted significant research effort in recent years. These types of systems are characterized by a topologically protected groundstate degeneracy, that gives rise to nonAbelian exchange statistics between the quasiparticles (1); (2); (3). The fractionalization of fundamental degrees of freedom into such exotic excitations and their nontrivial statistics is interesting both from a theoretical point of view and also as a potential basis for quantum computation (4); (5); (6).
Over the years, different proposals for realizing and observing this type of phenomenon in solidstate systems were laid out, among others surfaces of topological insulators (7), semiconductor wires (8); (9), edges of fractional quantum Hall systems or quantum spinHall systems (10); (11), and interacting nanowires (12); (13). One such setup is a Josephson junction comprised of the edge of a quantum spinHall insulator with time reversal symmetry breaking Zeeman splitting (14). The periodicity of the Jospheson current with the phase across the junction is replaced by periodicity, reflecting the existence of weakly coupled Majorana fermions that allow for singleelectron transfer between the superconducting banks. This proposal, and the clear signature it promised, led to a focus of experimental efforts to observe periodic Josephson currents, in what came to be known as fractional Josephson junctions (15); (16); (17).
The absence of time reversal symmetry in the junctions is central to the stability of the Majorana bound states and to the observation of the periodicity. The physics of time reversal symmetric topological Josephson junctions was studied by Zhang and Kane (18) and by Orth et al. (19) who observed that interactions between the electrons in the junction lead to periodicity of the supercurrent as a function of the phase bias across the junction. Similar to the association of the periodicity with Majorana fermions that allow tunneling of single electrons across the junction, these authors relate the periodicity to parafermions that allow the tunneling of fractional charges. In this context, it is convenient to view the Majorana bound states as parafermions. However, in order for the lowenergy physics to be adequately described by these parafermions, the setup considered by these authors requires very strong electronelectron interactions in the junction. The strong interactions in the junction favor the formation of magnetic order, and the domain wall between regions with magnetic order and regions with superconducting order carry the parafermions. This is similar to other suggestions for realization of parafermions, on the edges of fractional quantum Hall states that are coupled alternately to ferromagnets and superconductors (10); (11).
Recently, an alternative route to periodicity in topological Josephson junctions was suggested by Peng et. al. (20) and by Hui and Sau (21). These authors showed that a weak exchange interaction between the edge electrons and a quantum impurity spin, without breaking time reversal symmetry, leads to a similar periodicity of the current. The question of strong exchange interactions was not directly addressed in these papers, which explicitly assumed weak coupling with respect to the superconducting gap. The analogy between the two models in the weak coupling regime naturally suggests that a similar resemblance holds in the strong coupling regime, and that the lowenergy effective Hamiltonian in that case will give rise to stable parafermions.
Here we study time reversal symmetric junctions strongly coupled to an impurity spin as an experimentally accessible system for constructing and detecting parafermions. We show that even for weak electronelectron interactions, the coupling to the local impurity might lead to the formation of such parafermions, and study the different local coupling parameters that control whether they will appear. We continue by characterizing these parafermions and the fourfold degenerate groundstate subspace they span, as well as their signature on physical features such as the periodicity of the current as a function of the phase bias across the junction and charge tunneling.
The impurity may be realized in experiment using a quantum dot in proximity to the edge. Such devices would allow for relatively high control over microscopic parameters and are accessible to readout and measurement. As the parafermions are composed not only of the edge electrons but also of the impurity (dot) degrees of freedom, we believe that this feature may open experimental opportunities to detect and possibly manipulate these exotic particles.
The remainder of the paper is organized as follows. We begin, in Sec. II, by reviewing the underlying physical picture and the main results of the paper. Then in Sec. III we introduce the setup and map its Hamiltonian onto a bosonized version with conjugate superconducting and magnetic order parameters. We apply a renormalization group analysis of the bosonic Hamiltonian in Sec. IV, and study the different strongcoupling regimes that may describe the lowenergy behavior of the system, depending on the microscopic parameters. We then proceed to study the strongbackscattering limit in Sec. V. We establish the groundstate degeneracy, construct the parafermion operators, and study their properties. Finally, in Sec. VI we relax the strongbackscattering limit in order to study the tunneling between different states in the groundstates manifold and the relation to the periodicity of the junction.
Ii Review of the Basic Physical Picture and Results
In this section we aim to cover the basic physics of the proposed setup and present the main results, with as little technical details as possible. These we leave to the more detailed analysis and calculations that will follow in later sections.
We study a setup consisting of an edge of a quantum spin Hall insulator, with a helical pair of counterpropagating edge modes. The junction connects parts of the edge that are in proximity to BCS superconductors, creating a Josephson junction. In addition to that, the edge modes in the junction are coupled by exchange interaction to an impurity spin. We draw a schematic picture of the setup in Fig. 1. The entire setup is time reversal symmetric, but all other symmetries, in particular spatial symmetries that pertain to the coupling between the edge electrons and the impurity, are assumed to be broken. The lack of spatial symmetry can be the result of the impurity spin representing an accidental charge puddle along the edge (22), or engineered as part of a setup where the coupling to the impurity is an effective representation of coupling to a quantum dot put in proximity to the edge.
Previous studies of time reversal symmetric topological Josephson junctions without coupling to a spin reported that interactions between the electrons in the junction opens a gap in the manybody spectrum, whose signature is the periodicity of the current with the phase bias across the junction (18); (19). Strong pair backscattering within the junction favors magnetic order of the edge electrons, and gaps the entire junction. The condition for the magnetic order to appear is that the pair backscattering term is relevant, from a renormalization group point of view. This happens for a sufficiently long junction if the electronelectron interactions are strong such that the Luttinger parameter describing them maintain .
In junctions with broken time reversal symmetry, a doubly degenerate ground state is related to two possible fermion parities in the junction, and the degeneracy is captured by a pair of Majorana fermions, whose joint occupancy decides the fermion parity (14). The degeneracy is lifted due to the weak coupling of the Majorana fermions across a finite junction. Maintaining time reversal symmetry augments the degeneracy caused by the fermion parity, as pairs of time reversed states are also degenerate. These states pertain to different magnetic orders in the junction, and their degeneracy gives rise to a fourfold degenerate groundstate space, which is appropriately described by parafermions. The degeneracies are lifted as the parafermions are weakly coupled, allowing tunneling of fractional charge across the junction, with the weakness of the hybridization ensured by the gap along the entire junction.
Addressing the setup we present here, it is not at all evident that a similar gap can open as a result of coupling to an impurity. While the pair backscattering term acts along the entire length of the junction, the coupling to the impurity is limited to a single point in space. However, previous studies of impurities in Luttinger liquids, most notably those by Kane and Fisher (23), show that the backscattering from an impurity is relevant for any repulsive interaction between the electrons , and the backscattering term increases in magnitude under the renormalization group flow. The strong coupling regime is that of infinitely strong backscattering, effectively separating both sides of the impurity into two independent Luttinger liquids.
The exchange interaction between the electrons and the impurity spin is not only subject to the flow described by Kane and Fisher, but also to Kondo physics. In contrast to the strong backscattering regime, in the Kondo strong coupling regime the impurity favors forming a singlet state with the edge electrons, resulting in the complete screening of the impurity and the reconstitution of the edge modes around the impurity site (24); (25).
The competition between these two strong coupling regimes is decided based on the strength of the electronelectron interactions in the junction, encoded in the Luttinger parameter , and on the bare anisotropy of the exchange couplings. Strong interactions and strong anisotropy will favor the strong backscattering regime, while the Kondo flow tends to erase any initial anisotropy and lead to an isotropic strong coupling fixed point that is characterized by a singlet.
In addition to the exchange couplings, the system is also defined by energy scales pertaining to the junction itself. These are the superconducting gap and the level spacing of the subgap Andreev states located in the junction. These scales will generally cut the renormalization group flow before it reaches one of the strong coupling fixed points, even at zero temperature. In case that they are the largest energy scales, the exchange coupling will not renormalize and will remain weak, allowing for a perturbative treatment. This regime was studied in detail in Refs. (20) and (21) and will not be considered here. The cutting of the flow means that the system will reside in the vicinity of one of the strong coupling fixed points (or stay in the weak coupling regime, if and are large,) and the lowenergy physics will be determined by the perturbations within each regime.
A schematic picture of a typical renormalization group flow of the backscattering strength is given in Fig. 2. For , the relative strength of the backscattering initially increases exponentially at rate , but as the flow continues the Kondo physics eventually tends to dominate and decreases to zero. For the noninteracting case there is no increase and will always decrease until the backscattering is suppressed by singlet formation and screening of the impurity. If the renormalization group flow stops at a point where is the largest energy scale, the system will reside in the strong backscattering regime. On the other hand, if the flow stops after has decreased to small values, the system will be in the Kondo regime. A schematic depiction of all three regimes – the weak exchange coupling, the Kondo regime, and the strong backscattering regime – is given in Fig. 3. An exact flow diagram for several different bare values of the exchange coupling and different values of will be discussed in Sec. IV.
In the strong backscattering regime the setup favors magnetic order of the edge electrons about the impurity. Similar to the strongly interacting regime studied by Zhang and Kane, the boundaries between the magnetic and the superconducting order give rise to parafermions, which are located to the left and to the right of the impurity. A unique feature of these parafermions is that they are not composed solely of the edge electrons degrees of freedom but also contain parts that pertain to the impurity spin. These parafermions allow for coherent tunneling of a fractional charge across the junction.
In the limit of infinite backscattering, the groundstate subspace is fourfold degenerate. Relaxing this limit, the parafermions weakly couple and tunneling between the different states is allowed, lifting the degeneracies. The tunneling terms are exponentially small in . The tunneling is also dependent on the phase bias across the junction, and the energy spectrum as a function of the phase bias is given in Fig. 4(a). This dependence gives rise to periodicity of the current as a function of the phase.
The different states in the groundstate manifold correspond to different fermion parity and different magnetic order. The latter is potentially experimentally accessible by measuring the orientation of the impurity spin, or the appropriate corresponding quantity in a quantum dot that acts as the impurity. A flip in the orientation of the impurity spin is associated with a tunneling of charge across the junction, in a similar manner to the phenomena in which a full rotation of a classical magnet that gaps the edge of a topological spin Hall sample pumps an electron across the gapped region (26); (27); (28); (29). This phenomenon is present also in the absence of superconductivity, see Refs. (30); (25). We believe that this allows the observation and measurement of such parafermions using realistic devices.
(a) 
(b) 
As a final comment, we point out that the lowenergy physics in the Kondo strong coupling regime is similar to the one in the weak coupling regime studied in Refs. (20) and (21). The screened impurity induces weak local spinspin interactions between the edge electrons themselves. The lowenergy manybody spectrum, seen here in Fig. 4(b), is once again periodic as a function of the phase bias. Similarly to the weak coupling regime, the level crossings that give rise to this periodicity are protected by fermion parity conservation and timereversal symmetry. This strongtoweak duality is an interesting effect which is covered in Sec. IV.2.
Iii Model and Bosonization
We consider a quantum spin Hall edge of length , with edge modes counterpropagating with velocity , placed between two superconducting leads with superconducting gap and phase difference (see Fig. 1). The helical edge modes are then described by the Hamiltonian with dccclxxx^{(31)}
(1) 
where for up (down) spins and
(2) 
is the proximityinduced superconducting potential acting only outside the junction region. The effective Coulomb interaction between the electrons on the edge is taken to be shortranged , and to act between the charge densities
(3) 
where denotes normalordering of the operators. Generally, the Coulomb interaction is screened underneath the superconducting contacts, so that we assume to be of the form . For phase bias this edge Hamiltonian is time reversal symmetric, as defined by the transformation
(4) 
The edge of the quantum spin Hall insulator is generally not clean, with disorder and impurities present. Electronic puddles along the edge may act as an effective impurity spin that will couple to the edge modes (22). Alternatively, one may also consider a setup where a quantum dot is intentionally put in proximity to the edge in a controllable manner. The coupling to the dot can be described effectively as an exchange coupling with an impurity spin. To account for such a coupling we consider a localized impurity spin at the origin , described by the exchange Hamiltonian
(5) 
Here , with the relevant Pauli matrix and the electronic spinor, is the component of the electronic spindensity. Moreover, the account for spin anisotropy. The coefficients are arbitrary exchangecoupling coefficients which we assume to be random (but fixed.) The arbitrariness of the exchange couplings removes all symmetries besides time reversal symmetry, which is preserved since . The main results we shall derive are independent of the magnitude of the spin. However, for definiteness, we shall consider the case of a spin impurity, and comment where the generalization to higher spins is not immediate. Therefore, we omit the spin anisotropy contributions to in the meantime.
iii.1 Abelian Bosonization
Our goal now is to map the Hamiltonian of Eqs. (1) and (5) onto a bosonized one corresponding to two conjugate degrees of freedom that describe superconducting and magnetic order. To this end, we start by bosonizing the fermionic fields , which according to the standard prescription (32) can be written as
(6) 
where are bosonic fields and is a shortdistance cutoff associated with the electronic bandwidth by . These bosonic fields obey the commutation relations
(7) 
and the identity applies. The transformation of the fields under time reversal is derived from the transformation of the corresponding fermionic fields given in Eq. (4), which dictates
(8) 
The different terms in the Hamiltonian are now written using these bosonic fields as
(9) 
and we divide into backscattering and forward scattering terms with dccclxxx^{(33)}
(10) 
It is natural to introduce the linear combinations and . These fields are a conjugate pair, as they obey the commutation relations
and
(11) 
The derivatives of these fields give the physical chargedensity and spindensity , with the charge of the electron. Under time reversal these fields transform as
(12) 
These fields allow us to write the Hamiltonian in a more compact form
(13) 
where we have adopted a vector notation for the coupling constants . Assuming to be constant in space throughout the junction, , it defines the Luttinger parameter , with corresponding to repulsive interactions and to attractive interactions. The free part of the Hamiltonian inside the junction is then written in the usual manner as
It is the Hamiltonian of Eq. (13) that will be our main point of interest in most of the paper.
Iv Perturbative Renormalization Group Analysis
In order to study the lowenergy properties of the model, we apply a perturbative renormalization group analysis to it. For clarity and brevity, we relegate the detailed calculations to App. A and present here their results.
iv.1 Weak Coupling Fixed Point
The leading order renormalization group flow equations about the weak coupling fixed point follow from the results of Kane and Fisher(23) on impurities in Luttinger liquids. These results describe relevant (irrelevant) backscattering for repulsive (attractive) interactions. The leading order equations are given by
(14) 
where , with the bare bandwidth and the running bandwidth scale, and we assumed a uniform Luttinger parameter throughout the junction. In addition, the superconducting gap , assuming that the interactions are screened in the superconducting region, obeys the flow equation .
These results are in agreement with previously known results for magnetic impurities in Luttinger liquids (34); (35); (36); (37); (38). For any repulsive interaction the backscattering Hamiltonian is relevant, flowing to the strong coupling regime, and irrelevant for attractive interactions. The forward scattering is marginal to leading order. Finally, the induced superconducting gap is relevant.
The exchange coupling also leads to Kondo behavior, captured by the secondorder terms in the flow equations. These terms are of the form (see App. A)
(15) 
where the on the righthandside stand for the linear terms in Eqs. (14). The secondorder perturbation also gives rise to new terms that represent twobody interactions at the origin, such as , etc. These terms are irrelevant near , and we omit them. We note that for the pair backscattering may play an important role, as it becomes relevant (39); (40); (37); (25). For interactions of this strength, one also has to consider the bulk pairbackscattering which is relevant for . Such strong values of were discussed in Refs. (18) and (19) and we will not consider them here. The coefficients in Eq. (15) are of order unity and depend on the cutoff scheme. For a hard cutoff of momenta at , associated with the energy bandwidth , they are given by
(16) 
where
(17) 
which results in positive near . To corroborate this picture we also conducted a poor man’s scaling analysis to the original electronic Hamiltonian in the noninteracting regime, reaching equivalent equations to second order in the exchange coupling.
We stress here that while the results of the leading order are independent of the magnitude of the spinimpurity , in deriving the second order terms we explicitly restricted ourselves to . Larger impurity spins will lead to modified flow equations in the secondorder, which will include corrections to the spin anisotropy terms as well.
The linear terms in the flow equations increase the exchange couplings and at the same exponential rate in , driving both to a strong backscattering fixed point while maintaining their orientation and the ratio between them. The second order terms, however, drive the flow toward the Kondo fixed point, characterized by an isotropic exchange coupling and for all . At this point the exchange interaction is proportional to , and the ground state is a singlet.
To see this, we set , thus taking into account only the second order terms. We identify the three constants of motion . As the magnitudes of all increase, the cosine must decrease to zero. Therefore , and we conclude that all the exchange coupling vectors become orthogonal to each other. Similarly is also a constant of motion, hence the difference in magnitude between the different exchange couplings becomes negligible in the strong coupling regime.
Strong backscattering is the result of pinning to a value which minimizes the energy of in Eq. (13). At the isotropic point, however, serves as a rotation angle and can be eliminated from by a unitary transformation, corresponding to the absence of backscattering. To quantify the strength of the backscattering, we examine the dependence of the eigenenergies of in Eq. (13) on . For a spin impurity, the energies are given by with
(18)  
At the isotropic point becomes completely independent of . Following this, we can characterize the magnitude of the anisotropy by
(19) 
which is zero at the isotropic point and increases with the anisotopry.
Under the linear terms of the flow equations, will grow exponentially for repulsive interactions, as . Under the second order terms, however, the numerator in the expression for is a constant of motion, while the denominator grows, and will decrease. As two extreme cases one may consider on the one hand a setup in which only , and the other exchange couplings vanish. In this case, the Kondo flow is absent and the backscattering increases exponentially. On the other hand, starting from the perfectly isotropic point where , the system will remain isotropic throughout the renormalization process and no dependence on will emerge.
The competition between these two directions determines whether the strongcoupling regime that the system will find itself in at the end of the renormalization group flow will be characterized by strong anisotropic backscattering or by Kondo screening of the impurity. This competition is decided by the values of the initial bare anisotropy, the strength of the interactions encoded in and finally, by the point at which the renormalization flow stops, which depends also on the junction’s energy scales and and on the bandwidth . In Fig. 5 we plot several examples for the flow of as a function of under different initial conditions and values of . Initially increasing exponentially, generally starts decreasing at some point once the second order terms become dominant. However, it may attain a relatively large value before it starts to decrease, and the flow may stop at that point. As the perturbative flow equations are strictly applicable only in the weak coupling regime, we note that this is a qualitative picture, and a more precise analysis calls for numerical tools, which are beyond the scope of this work. However, as we shall show below, both regimes are stable.
Below we discuss these two possible strong coupling regimes, and describe their lowenergy physics. We will address briefly the Kondo strong coupling regime, before devoting the main part of the discussion to the strong backscattering regime, which gives rise to parafermions.
iv.2 Kondo screening regime
In the strong Kondo coupling regime, the renormalization group flow of the exchange couplings tends to form an isolated singlet of the impurity spin and the adjacent electrons of the edge. The helical nature of the edge does not allow for backscattering from the pure singlet, and the edge will reconstitute itself around the singlet (24); (25). However, the presence of the junction’s energy scales and mean that the system will not be exactly at the Kondo fixed point even at zero temperature, as the flow will be cut before it reaches that point, and the irrelevant operators about the fixed point will determine the lowenergy behavior of the system.
Even though the exchange couplings at the fixed point are isotropic, the anisotropic nature of the bare exchange couplings will have a weak residual effect on the edge electrons. This can be seen by carrying out a strongcoupling expansion about the singlet state with the anisotropic terms as perturbations. The leading terms in that expansion, after projecting onto the singlet, can be written as
(20)  
where time reversal symmetry constrains the coefficients to be real and to satisfy , and we have used pointsplitting in order to avoid violation of the Pauli principle (25).
In terms of the bosonic fields the first term will be proportional to and is marginal for all to leading order. The second term will consist of operators involving four bosonic fields, and their derivatives, such as etc. These operators are irrelevant for any , and can be treated as weak perturbations about the fixed point.
As in the weak coupling limit (20); (21), it is constructive to work in the electronic picture, effectively taking the noninteracting limit, and projecting onto the lowenergy space spanned by the Andreev bound states. The finite dimensional Hamiltonian is then diagonalized exactly for any phasebias , and the spectrum is plotted. We carry out the detailed calculation in App. B, and present here only the result, shown in Fig. 4(b). For a long enough junction the exchange interaction opens gaps in the manybody spectrum, leading to periodicity of the Josephson current. The strongtoweak duality can be understood in the following manner. The screening of the impurity decouples it from the edge, but the screening is not perfect and leaves residual weak spinspin interactions. These weak interactions have a similar effect to the ones considered in Ref. (18).
iv.3 Strong backscattering regime
For , the backscattering terms in the Hamiltonian of Eq. (13) are relevant to leading order, while the forward scattering term is marginal. Depending on the bare values of the exchange couplings, the renormalization group flow might stop at a point where the largest energy scale is the backscattering term. In order for this to be the case, the setup must have a strong bare anisotropy in the exchange couplings.
To simplify the discussion in this section, we shall consider the strong local backscattering Hamiltonian to be of the form , corresponding to the electronic term . This, in fact, is not a restrictive choice, as the basis for the impurity spin can always be chosen such that this local term will be parallel to , and we can also apply a rotation about the axis of the edge electrons’ spin, such that the backscattering term will be in the direction. This is tantamount to a constant shift of the field, which does not affect the kinetic term.
In the limit of infinitely strong backscattering , the junction is cut into two disconnected halves by the impurity (23). The field at the origin is pinned by the backscattering term, and its value is related to the orientation of the impurity spin. The presence of the superconductors makes defined modulo , which renders the ground state fourfold degenerate, as , , and all have the same energy , ( is the magnitude of the impurity spin.) This fourfold degeneracy of the ground state is not accidental, but directly related to the time reversal symmetry of the system. Indeed, under a time reversal transformation, and , which relates the different ground states to each other. As the field at is pinned to one of four possible values, we may write it as
(21) 
with an integervalued operator. The parts of the edge to the left and to the right of the impurity are now described by independent fields and , with the constraint .
To establish the stability of the strong backscattering fixed point, we carry out a strongcoupling expansion about it, by considering the local exchange and the kinetic terms as perturbations. Projecting onto the groundstate manifold we get that the leading terms are given by
(22)  
where is the dynamical term connecting both sides of the impurity, and the different coupling coefficients are determined by the values of and .
The terms in Eq. (22) can be understood by considering the different constraints on the expansion. As is pinned, the local dynamical degrees of freedom are and the spin. As such, the only timereversal invariant local perturbations are (i) , which describes tunneling of an electron between the two liquids, (ii) and , which describe tunneling via interaction with the impurity spin, and (iii) the potential scattering . The projection onto the ground state allows for spin flips of the impurity only when they are combined with shifting of by halfinteger multiples of . As all local processes describe tunneling of full electrons, they change the value of by integer multiples of , and therefore cannot connect states with different values of the local spin. The projection onto the groundstate manifold leaves only the component of , and casts as identical to . We shall see below that the terms that connect states with different spin orientations are nonperturbative.
The renormalization group flow equations for the operators in Eq. (22) are
(23) 
where is the running cutoff. For repulsive interactions the operators are irrelevant and is marginal, therefore the fixed point is stable under local perturbations. We now turn to study the lowenergy physics in the vicinity of the strong backscattering fixed point, with an emphasis on the interplay with the superconductivity.
V Infinite backscattering limit and Parafermions
We shall focus now on the regime where the exchange coupling to the impurity spin causes infinitely strong backscattering, effectively cutting the junction into two halves. As discussed before, is fixed by the strong backscattering, and further generalizing Eq. (21) we write
(24) 
where is fixed and defined by the exact form of the backscattering terms such that , given in Eq. (18), is maximal at . The dependence of the potential on and the impurity spin orientation can be seen in Fig. 6(a).
Outside the junction, the superconducting pairing pins to the minimum of the potential and we may expand it similarly to as
(25) 
where are integer valued operators as well. It should be pointed out that and do not commute, , and the system cannot be in an eigenstate common to both operators. On the other hand, and commute, see Eq. (11).
The fourfold degeneracy of the ground state gives rise to parafermion operators, associated with the tunneling between the different ground states. The parts of the junction to the left and to the right of the impurity are then domain walls between a region with superconducting order ( is pinned) and magnetic order ( is pinned). To derive the corresponding operators we follow a procedure similar to Ref. (11). The free Hamiltonian on the left and on the right hand side of the impurity is written as with
(26) 
and the fields are subject to the boundary conditions
(27) 
These fields can be expanded in their eigenmodes separately in the sections to the left of the impurity as
(28)  
and to the right of the impurity as
(29)  
where , and the are canonical bosonic operators . Then, the Hamiltonian in each sector reduces to free bosonic modes
(30) 
with the spectrum . In addition it also supports a zero mode . We write explicitly
(31) 
where operates in the impurityspin space alone and flips the spin. For spin , and the generalization to larger spins is immediate. The asymmetry between the operators and originates from the commutation relation in Eq. (11), which gives a nontrivial commutation relation between and but a trivial one between and . One can directly verify that these operators commute with the Hamiltonian in the infinite backscattering limit, and are therefore zero modes. As the operators satisfy the commutation relation
(32) 
and have the property that , they are parafermions. The tunneling between the different states in the groundstate manifold is described by the operator , which induces the transformation
(33) 
while remain unchanged by the transformation. The phase ensures that under time reversal transforms as .
This tunneling operator carries a fractional charge across the junction, as the charge density is the derivative of the field. To see this explicitly, one can examine the charge to the left and right of the impurity by defining
(34) 
and a direct calculation gives
(35) 
It should also be noted that can be written using the original electronic degrees of freedom, using the identity , which recasts it as
(36)  
with . This form emphasizes the manybody nature of the parafermionic state. We elaborate on the manybody fermionic picture in App. C.
Vi Relaxing the strong backscattering limit
For infinite the value of is pinned to one of the four values of the ground state and the fourfold degeneracy is perfect. Relaxing this condition will allow finite coupling between the different states in the groundstate manifold, lifting some of the degeneracies. The strong backscattering induces a potential barrier for the field (see Fig. 6), and the coupling between the states within the ground state manifold arises from two separate and independent contributions. The first one is tunneling between adjacent minima through the barrier, which can be calculated nonperturbatively by instanton methods. We label the amplitude of such tunneling events by . The second contribution is tunneling between nextadjacent minima, whose values are separated by , and we label its amplitude by . For simplicity, we omit from the Hamiltonian the lessrelevant forward scattering term (see Sec. IV).
Tunneling between adjacent minima requires the flipping of the spin, while tunneling between nextadjacent minima does not. Therefore, will be the dominant contribution when the exchange couplings are such that the impurity spin tends to follow the configuration of the edge electrons encoded in , while will be the dominant one when the spin tends to remain fixed, allowing only for single electrons to tunnel through without flipping. In the general case both of them will coexist in the effective lowenergy Hamiltonian.
In order to evaluate , we start from the backscattering Hamiltonian of Eq. (13), and write defined in Eq. (24) explicitly as
(37) 
and the maximal energies are given by
(38)  
For spin, for each value of there are two eigenvalues of , given in Eq. (18), corresponding to opposite orientations of the impurity spin. Assuming , the two levels are separated for every (there are no degeneracies), and the height of the potential barrier separating adjacent minima is
(39)  
The role of the kinetic term that drives is taken by a term that does not commute with . The first natural candidate for such a term is the relevant superconducting pairing at , expressed in terms of the field, which has nontrivial commutation relations with . However, the superconducting pairing is of the form , which can only induce a shift of , as a Cooper pair tunnels across the junction. Therefore it commutes with and cannot give rise to tunneling between different minima.
We turn then to consider the kinetic term . This term has non trivial commutation relations with as , subject to the regularization , with the shortdistance cutoff. Keeping from the integral in the kinetic term only the derivative at , we are left with , and we define our pseudokinetic energy, driving , as
(40) 
The contribution of a single instanton to the matrix element between two adjacent states, and therefore to , is proportional to with the action of the classical path starting at and ending at , under the inverted potential . In order to evaluate the action in analytical form, we first assume that the dynamics of the spin is much faster than the dynamics of the local field . Under this assumption we can take the adiabatic limit in which the spin follows the effective magnetic field
(41) 
at each point [see Fig. 6(b).] We have thus mapped the problem to a tunneling problem of between minima of the periodic potential given by
which can be seen in Fig. 6(a). The action along the classical path in the adiabatic limit is given by
(43)  
We have also calculated the action numerically, taking into account the full dynamics of the impurity spin, and verified that the action scales with even when the adiabatic limit is not taken explicitly (see Fig. 7).
The exponential dependence is the dominant scaling of the tunneling amplitude
(44) 
and we will not evaluate the prefactor to . As is exponentially small in , for strong backscattering the degeneracy lifting is small. This parameter can be increased by working with spins larger than , as the height of the potential barrier between the wells depends linearly on the size of the spin.
In the calculation above we omitted the forward scattering term . In the instanton language formulated here, this term is equivalent to a term linear in which is coupled to the local impurity spin. While a term solely linear in will not affect the calculations, as it can be effectively incorporated into the quadratic term by a constant shift in the definition of , the coupling to the impurity spin degrees of freedom means that it will also affect its dynamics. Adding this term changes the classical equations of motions for the spin degrees of freedom to be
(45) 
The magnitude of can be evaluated by , therefore the added term can be neglected as long as . Since is relevant, while is marginal, this assumption is justified, and we may omit this term altogether.
We turn to evaluate , which correspond to tunneling between nextadjacent minima. This type of process does not require the spin to flip, and will be dominant when the spin does not easily follow the instantaneous configuration of the electrons. One can therefore fix the spin orientation and solve the problem of tunneling through a barrier, a task which is done in App. C, and which yields the scaling
(46) 
The lowenergy subspace is separated from the rest of the spectrum by three distinct gaps:

A gap of size separating it from excitations associated with the magnetic orientation of the impurity spin at , fixing the orientation of the impurity spin and of the edge electrons.

A gap of size separating it from quasiparticle excitations in the superconducting leads.

A gap of size separating it from excitations of the free modes inside the junction itself.
In order for the parafermions to remain protected even for finite , we require that and will be much smaller than these gaps. This is achieved in the limit .
Assuming that the system resides in the regime where the ground state manifold is well separated from the rest of the spectrum, the Hamiltonian within the groundstate manifold can be written using the operator that tunnels between adjacent states within the subspace, as