Experimental Observation of a Generalized Thouless Pump with a Single Spin
Adiabatic cyclic modulation of a one-dimensional periodic potential will result in quantized charge transport. Such a pump is termed the Thouless pump. In contrast to the original Thouless pump restricted by the topology of the parameter space, here we experimentally observe a generalized Thouless pump that can be extensively and continuously controlled. The extraordinary features of the new pump originate from interband coherence in nonequilibrium initial states, and this fact indicates that a quantum superposition of different eigenstates individually undergoing quantum adiabatic following can also be an important ingredient unavailable in classical physics. Additionally, because the pumping is most pronounced around a band-touching point, this work also offers a nonequilibrium means to detect quantum or topological phase transitions. The quantum simulation of this generalized Thouless pump in a two-band insulator is achieved by applying delicate control fields to a single spin in diamond. The experimental results demonstrate all principal characteristics of the generalized Thouless pump.
In 1983, Thouless discovered that the charge transport across a one-dimensional lattice over an adiabatic cyclic variation of the lattice potential is quantized, equaling to the Chern number defined over a two-dimensional Brillouin zone formed by quasimomentum and time ThoulessPump1 (). This phenomenon, known as the topological charge pump or Thouless pump, shares the same topological origin as the quantization of Hall conductivity TKNN1 (); TKNN2 (); TKNN3 () and may thus be regarded as a dynamical version of the integer quantum Hall effect DQHE1 (). In the ensuing years, the theory of the Thouless pump was investigated extensively TKNN3 (). Up to now, several single-particle pumping experiments have been implemented in nanoscale devices PumpNanoExp1 (); PumpNanoExp2 (); PumpNanoExp3 (); PumpNanoExp4 (). Most recently, the topological Thouless pump was observed in cold atom systems PumpCdAtExp1 (); PumpCdAtExp2 (). On the application side, the Thouless pump has the potential for realizing novel current standards PumpApp1 (); PumpApp2 (), characterizing many-body systems PumpInt1 (); PumpInt2 (); PumpInt3 (); PumpInt4 (); PumpPhoton (), and exploring higher dimensional physics PumpHighD1 ().
In Thouless’ original proposal and almost all the follow-up researches, the initial-state quantum coherence between different energy bands, namely, the interband coherence in the initial states, is not taken into account. As a fundamental feature of quantum systems Schroedinger (); Quantify (), quantum coherence is at the root of a number of fascinating phenomena in chemical physics CC1 (); CC2 (); CC3 (), quantum optics QO1 (); QO2 (); QO3 (); QO4 (), quantum information Chuangbook (), quantum metrology Metrology1 (); Metrology2 (); Metrology3 (), solid-state physics Solid1 (); Solid2 (), thermodynamics Therm1 (); Therm2 (); Therm4 (); Therm5 (); Therm6 (), and even biology QB1 (); QB2 (); QB3 (). Therefore, a question naturally arises as to how the pump will behave if the interband coherence resides in the initial state. In this work, we generalize the Thouless pump by incorporating the interband coherence into the initial state, and hence present a quantum adiabatic pump distinct from the conventional Thouless pump.
The effect of the interband coherence in the initial state can be preliminarily evaluated by taking a qualitative analysis of the quantum adiabatic evolution. For the initial states without interband coherence, the cyclic adiabatic operation of duration induces a population correction of the order and an interband coherence of the order . These nonadiabatic effects, albeit vanishing in the adiabatic limit, are crucial to yield the quantized transport determined by a weighted integral of the Berry curvature ThoulessPump1 (); TKNN3 (). However, for adiabatic following of superposition states, the interband coherence in the initial states generically induce a population correction of the order to each band, in contrast to the usual population correction (see Fig. 1). This underlying mechanism indicates that if a quantum system accommodates interband coherence from the very start as a quantum resource, then the ensuing pumping may have unforeseen features. Intriguingly, the amount of transported charges contributed from the initial interband coherence is found to be finite in the adiabatic limit, namely, . In particular, in contrast to the original quantized Thouless pump subjected to the topology, the generalized Thouless pump fueled by interband coherence can be continuously and extensively controlled by varying the switching-on rate of a pumping protocol. The feature of tunability is reminiscent of the famous Archimedes screw, where water is pumped via rotating a screw-shaped blade in a cylinder and the amount of pumped water can also be changed continuously Archimedes1 (); Archimedes2 (); Archimedes3 (). Furthermore, the generalized Thouless pump is even more efficient around a band-touching point, thus offering a nonequilibrium means to detect quantum and topological phase transitions.
Consider a one-dimensional two-band insulator model subject to an adiabatic cyclic manipulation. In the momentum () space, the insulator’s Hamiltonian slowly modulated with time is given by
where is the scaled dimensionless time, and are standard Pauli matrices. Throughout this paper, we take . The instantaneous spectrum of is gapless at when (). An adiabatic cycle can be realized by slowly varying from to . For a general initial state with reflection-symmetric populations in , the pumped amount of charge over one adiabatic cycle can then be found from the first-order adiabatic perturbation theory Messiah (); AdPt3 (); PumpWang (); PumpZhou (). Specifically, in the adiabatic limit (), the charge transport can be decomposed as , with
and originating from some transient effects associated with the initial state. Here and are band indices, states represent instantaneous eigenstates of with eigenvalue , and refer to matrix elements of the density operator and the velocity operator in representation of , and is the Berry curvature of the th instantaneous energy band of . The term is of least interest because it does not accumulate with the number of pumping cycles and independent of any aspect of a pumping protocol (see Supplemental Material SM ()). The pumping component represents a weighted integral of the Berry curvature, as found previously by Thouless ThoulessPump1 (). The pumping component , namely, the charge pumping induced by interband coherence in the initial state, is responsible for the generalized Thouless pump and will be the focus of our experimental study below. Because the initial state considered here is always symmetric in , is unrelated to any symmetry breaking of the initial state. Rather, analogous to the conventional Thouless pumping, it arises from an accumulation of small nonadiabatic effects during the pumping. Note that derived in the adiabatic limit () diverges at quantum or topological phase transition points where the two bands touch each other. However, in actual experiments the duration of an adiabatic cycle is always finite and hence there is no true divergence in physical observations.
The generalized Thouless pump can be experimentally realized on a qubit system because the insulator’s Hamiltonian in Eq. (1) is also the Hamiltonian of a qubit in a rotating field parametrized by and . That is, by mapping the two-band insulator’s Hamiltonian to that for a qubit in a rotating field, we can experimentally demonstrate the generalized Thouless pump using a single spin SpHfCherNumExp (). To highlight the contribution from , in our experiment the initial state is properly designed such that , i.e., the traditional Thouless pumping and the initial transient effect have no contribution. To demonstrate the sensitivity of to the switching-on rate of the pumping protocol, namely, , we consider two different adiabatic protocols with and . The first protocol depicts a linear ramp, whereas the second depicts a quadratic ramp with a vanishing switching-on rate at . Because is proportional to the term , one directly sees that the latter choice with zero switching-on rate will make in theory (within the first-order adiabatic perturbation theory). This fact is used in our experiment to not only achieve the tunability inherent in the generalized Thouless pump, but also confirm the negligible role of .
In our experiment, we use a negatively charged nitrogen-vacancy (NV) center in diamond. The single spins in NV centers are convenient to initialize and read out, have long coherence time, and can be manipulated with high precision. Indeed, due to these advantages NV centers are one main platform in studies of nanoscale sensing, quantum information, and fundamental physics Doherty (); Schirhagl (); Prawer (); Wrachtrup ().
The diamond we use is a bulk sample with the C nuclide at the natural abundance of about 1.1% and the nitrogen impurity less than 5 ppb. The NV center is composed of one substitutional nitrogen atom and an adjacent vacancy as shown in Fig. 2(a). Under an external magnetic field parallel to the symmetry axis of the NV center, the electronic ground state , which is a triplet state, can be described by the Hamiltonian , where the first term is zero-field splitting with MHz, the second term is Zeeman splitting with the gyromagnetic ratio MHz/G, is the spin- angular momentum operator of the direction, and is the magnitude of the magnetic field. In our experiment, the external static magnetic field is along the NV symmetry axis with the magnitude G. Such magnetic field enables both the NV electron spin and the host N nuclear spin to be polarized by optical excitation Jacques (); Sar (). As illustrated in Fig. 2(b), microwave generated by an arbitrary waveform generator drives the transition between the two levels and which compose a qubit, and the level remains idle due to large detuning. The spin state can be read out by optical excitation and red fluorescence detection. All the optics is performed on a home-built confocal microscope, and a solid immersion lens is etched on the diamond above the NV center to enhance the fluorescence collection Robledo (); Rong ().
In the experiment, the Hamiltonian in Eq. (1) is constructed in the rotating frame with the rotation angular frequency where is the resonant frequency of the qubit (see Supplemental Material SM ()). All our descriptions below are in this rotating frame. We work with MHz and MHz, and select several frequencies between to MHz for . In order to obtain the pumped charge for each value of , the double integral of the velocity expectation value over the first Brillouin zone needs to be evaluated. Since the pumped charge contributed from a certain , namely, , is independent of each other, they are measured separately in different runs of experiment. The pulse sequence for each is sketched in Fig. 2(c). At first the qubit is polarized to the state by a green laser pulse, and then the initial state is prepared by a resonant microwave pulse. From Eq. (3) one can see that might be small if the off-diagonal matrix elements associated with different are chosen without design. To maximize in the experiment, are properly prepared as depicted in Fig. 2(c) initial (). As elucidated in Supplemental Material SM (), such initial states also make and vanish. Once the preparation of is done, the qubit is subjected to the Hamiltonian . The evolution governed by lasts for some duration , during which the angle increases coherently according to a pumping protocol. Immediately after the evolution, one needs to measure the velocity . As shown in Fig. 2(c), the measurement comprises two steps, namely, a resonant microwave pulse and the subsequent laser illumination. The combined effect of the two steps amounts to the observation of , where is the spectral norm of and is time-independent. The above sequence is performed for a series of between and , and is repeated at least a hundred thousand times to obtain the expectation value. One can then have as a function of . Numerical integration over based on experimental data for discrete values of , multiplied by , yields the experimental value of . This procedure is repeated for different values of . As detailed in Supplemental Material SM (), it suffices to let our measurements cover half of the first Brillouin zone to compare with theory. Some experimental data with s and are instantiated in Fig. 3. The pattern of the normalized velocity depends strongly on , and so does the shape of . In particular, there is a significant charge transport for and , i.e., near the band touching point.
The integral of over yields the total charge thanks to a reflection symmetry for the specific initial states we choose. As illustrated by the orange curve and data points in Fig. 4(a), the pumped charge first rises and then declines as the parameter sweeps from to . Though the ramp time s is still not in the true adiabatic limit , the pumped charge as a function of bears strong resemblance with the theoretical curve for , with their differences well accounted for. In particular, because a diverging at occurs only for , the observed pumping for a finite s is not expected to shoot to infinity. The peak of is not precisely at , but has a rightward shift. In this linear ramp case, a non-perturbative theory can be developed (see Supplemental Material SM ()). The theoretical shift of the peak of as a function of is found to be , in good agreement with our observation. This clearly indicates that the observed peak shift is merely a finite- effect. For a shorter ramp time s as depicted by the green curve and data points in Fig. 4(a), the pumping peak slightly goes lower again and shifts further away from the exact phase transition point . Overall, the two pumping curves with s and s have a remarkable overlap with each other, thus supporting that to the zeroth order, the outcome of the generalized Thouless pump is independent of . We next investigate another pumping protocol with s. The initial switching-on rate of this pumping protocol now vanishes. In this case, we observe negligible pumping, as evidenced by the blue curve and data points in Fig. 4(a). The results for the second protocol confirm that the generalized Thouless pump can be extensively tuned by varying the switching-on rate of a pumping protocol. Finally, one may note the differences between experimental results and the simulation results [smooth orange, green, and blue curves in Fig. 4(a)] based solely on time-dependent Schrödinger equations. The experimental errors are mainly due to the imperfection of the microwave pulses. Nevertheless, in the presence of the unavoidable experimental errors, our experimental results have demonstrated all principal features of the generalized Thouless pump.
In conclusion, by incorporating interband coherence into the initial state as a powerful quantum resource, we are able to go beyond the traditional Thouless adiabatic pump. Using a single spin in diamond, we have experimentally demonstrated a novel type of quantum adiabatic pump, which is extensively and continuously tunable by varying the switching-on rate of a pumping protocol. The experimental results have also confirmed our theoretical findings PumpWang (); PumpZhou (). This work establishes a new means for the detection of band-touching and hence quantum or topological phase transition points, and enriches the physics of adiabatic pump and coherence-based quantum control.
The authors at USTC are supported by the 973 Program (Grants No. 2013CB921800, No. 2016YFA0502400, 2016YFB0501603), the National Natural Science Foundation of China (Grants No. 11227901, No. 31470835, and No. 91636217), the CAS (Grants No. XDB01030400 and No. QYZDY-SSW-SLH004, No. QYZDB-SSW-SLH005, No. YIPA2015370), the CEBioM, and the Fundamental Research Funds for the Central Universities (WK2340000064). The authors at NUS are supported by the Singapore NRF grant No. NRF-NRFI2017-04 (WBS No. R-144-000-378-281) and by the Singapore Ministry of Education Academic Research Fund Tier I (WBS No. R-144-000-353-112).
W. M., L. Z., and Q. Z. contributed equally to this work.
- (1) D. J. Thouless, Quantization of particle transport, Phys. Rev. B 27, 6083 (1983).
- (2) D. J. Thouless, M. Kohmoto, M. P. Nightingale, and M. den Nijs, Quantized Hall Conductance in a Two-Dimensional Periodic Potential, Phys. Rev. Lett. 49, 405 (1982).
- (3) M. Kohmoto, Topological invariant and the quantization of the Hall conductance, Ann. Phys. 160, 343 (1985).
- (4) D. Xiao, M.-C. Chang, and Q. Niu, Berry phase effects on electronic properties, Rev. Mod. Phys. 82, 1959 (2010).
- (5) V. Gritsev and A. Polkovnikov, Dynamical Quantum Hall Effect in the Parameter Space, PNAS 109, 6457 (2012).
- (6) M. Switkes, C. M. Marcus, K. Campman, and A. C. Gossard, An adiabatic quantum electron pump. Science 283, 1905 (1999).
- (7) M. D. Blumenthal, B. Kaestner, L. Li, S. Giblin, T. J. B. M. Janssen, M. Pepper, D. Anderson, G. Jones and D. A. Ritchie, Gigahertz quantized charge pumping. Nature Phys. 3, 343 (2007).
- (8) B. Kaestner, V. Kashcheyevs, S. Amakawa, M. D. Blumenthal, L. Li, T. J. B. M. Janssen, G. Hein, K. Pierz, T. Weimann, U. Siegner, and H. W. Schumacher, Single-parameter nonadiabatic quantized charge pumping. Phys. Rev. B 77, 153301 (2008).
- (9) J. M. Shilton, V. I. Talyanskii, M. Pepper, D. A. Ritchie, J. E. F. Frost, C. J. B. Ford, C. G. Smith and G. A. C. Jones. High-frequency single-electron transport in a quasi-one-dimensional GaAs channel induced by surface acoustic waves. J. Phys. Condens. Matter 8, L531 (1996).
- (10) S. Nakajima, T. Tomita, S. Taie, T. Ichinose, H. Ozawa, L. Wang, M. Troyer, and Y. Takahashi, Topological Thouless pumping of ultracold fermions, Nat. Phys. 12, 296 (2016).
- (11) M. Lohse, C. Schweizer, O. Zilberberg, M. Aidelsburger, and I. Bloch, A Thouless quantum pump with ultracold bosonic atoms in an optical superlattice, Nat. Phys. 12, 350 (2016).
- (12) Q. Niu, Towards a quantum pump of electric charges. Phys. Rev. Lett. 64, 18121815 (1990).
- (13) J. P. Pekola, O.-P. Saira, V. F. Maisi, A. Kemppinen, M. Mttnen, Y. A. Pashkin, and D. V. Averin, Single-electron current sources: Toward a refined definition of the ampere. Rev. Mod. Phys. 85, 1421 (2013).
- (14) E. Berg, M. Levin, and E. Altman, Quantized Pumping and Topology of the Phase Diagram for a System of Interacting Bosons, Phys. Rev. Lett. 106, 110405 (2011).
- (15) D. Meidan, T. Micklitz, and P. W. Brouwer, Topological classification of interaction-driven spin pumps, Phys. Rev. B 84, 075325 (2011).
- (16) D. Rossini, M. Gibertini, V. Giovannetti, and R. Fazio, Topological pumping in the one-dimensional Bose-Hubbard model, Phys. Rev. B 87, 085131 (2013).
- (17) F. Grusdt and M. Höning, Realization of fractional Chern insulators in the thin-torus limit with ultracold bosons, Phys. Rev. A 90, 053623 (2014).
- (18) J. Tangpanitanon, V. M. Bastidas, S. Al-Assam, P. Roushan, D. Jaksch, and D. G. Angelakis, Topological Pumping of Photons in Nonlinear Resonator Arrays, Phys. Rev. Lett. 117, 213603 (2016).
- (19) P. L. e S. Lopes, P. Ghaemi, S. Ryu, and T. L. Hughes, Competing adiabatic Thouless pumps in enlarged parameter spaces, Phys. Rev. B 94, 235160 (2016).
- (20) E. Schrödinger, Die gegenwärtige Situation in der Quantenmechanik, Naturwissenschaften 23, 807 (1935).
- (21) T. Baumgratz, M. Cramer, and M. B. Plenio, Quantifying Coherence, Phys. Rev. Lett. 113, 140401 (2014).
- (22) P. Brumer and M. Shapiro, Control of unimolecular reactions using coherent light, Chem. Phys. Lett. 126, 541 (1986).
- (23) D. J. Tannor, R. Kosloff, and S. A. Rice, Coherent pulse sequence induced control of selectivity of reactions: Exact quantum mechanical calculations, J. Chem. Phys. 85, 5805 (1986).
- (24) L. Zhu, V. Kleiman, X. Li, S. .P. Lu, K. Trentelman, and R. J. Gordon, Coherent laser control of the product distribution obtained in the photoexcitation of HI, Science 270, 77 (1995).
- (25) R. J. Glauber, Coherent and Incoherent States of the Radiation Field, Phys. Rev. 131, 2766 (1963).
- (26) M. O. Scully, Enhancement of the index of refraction via quantum coherence, Phys. Rev. Lett. 67, 1855 (1991).
- (27) A. Albrecht, Some Remarks on Quantum Coherence, J. Mod. Opt. 41, 2467 (1994).
- (28) D. F. Walls and G. J. Milburn, Quantum Optics (Springer-Verlag, Berlin, 1995).
- (29) M. A. Nielsen and I. L. Chuang, Quantum Computation and Quantum Information (Cambridge University Press, 2000).
- (30) S. L. Braunstein and C. M. Caves, Statistical distance and the geometry of quantum states, Phys. Rev. Lett. 72, 3439 (1994).
- (31) V. Giovannetti, S. Lloyd, and L. Maccone, Quantum metrology, Phys. Rev. Lett. 96, 010401 (2006).
- (32) V. Giovannetti, S. Lloyd, and L. Maccone, Advances in quantum metrology, Nature Photonics 5, 222-229 (2011).
- (33) Quantum Coherence in Solid State Systems, Proceedings of the International School of Physics “Enrico Fermi¡±, Vol. 171, edited by B. Deveaud-Pl¨¦dran, A. Quattropani, and P. Schwendimann (IOS Press, Amsterdam, 2009), ISBN: 978-1-60750-039-1.
- (34) C.-M. Li, N. Lambert, Y.-N. Chen, G.-Y. Chen, and F. Nori, Witnessing Quantum Coherence: from solid-state to biological systems, Sci. Rep. 2, 885 (2012).
- (35) L. H. Ford, Quantum Coherence Effects and the Second Law of Thermodynamics, Proc. R. Soc. A 364, 227 (1978).
- (36) L. A. Correa, J. P. Palao, D. Alonso, and G. Adesso, Quantum-enhanced absorption refrigerators, Sci. Rep. 4, 3949 (2014).
- (37) V. Narasimhachar and G. Gour, Low-temperature thermodynamics with quantum coherence, Nat. Commun. 6, 7689 (2015).
- (38) M. Lostaglio, D. Jennings, and T. Rudolph, Description of quantum coherence in thermodynamic processes requires constraints beyond free energy, Nat. Commun. 6, 6383 (2015).
- (39) J. Åberg, Catalytic Coherence, Phys. Rev. Lett. 113, 150402 (2014).
- (40) G. S. Engel, T. R. Calhoun, E. L. Read, T.-K. Ahn, T. Mančal, Y.-C. Cheng, R. E. Blakenship, and G. R. Fleming, Evidence for wavelike energy transfer through quantum coherence in photosynthetic systems, Nature (London) 446, 782 (2007).
- (41) E. Collini, C. Y. Wong, K. E. Wilk, P. M. G. Curmi, P. Brumer, and G. D. Scholes, Coherently wired light-harvesting in photosynthetic marine algae at ambient temperature, Nature 463, 644 (2010).
- (42) N. Lambert, Y.-N. Chen, Y.-C. Cheng, C.-M. Li, G.-Y. Chen and F. Nori, Quantum Biology, Nature Physics 9, 10 (2013).
- (43) B. L. Altshuler and L. I. Glazman, Pumping electrons, Science 283, 1864 (1999).
- (44) C. Rorres, The turn of the screw: optimal design of an Archimedes screw, J. Hydraul. Eng. 126, 72 (2000).
- (45) G. Müller and J. Senior, Simplified theory of Archimedean screws, J. Hydraul. Eng. 47, 666 (2009).
- (46) A. Messiah, Quantum Mechanics (North-Holland, Amsterdam, 1962), Vol. II, p. 752.
- (47) G. Rigolin, G. Ortiz, and V. H. Ponce, Beyond the Quantum Adiabatic Approximation: Adiabatic Perturbation Theory, Phys, Rev. A 78, 052508 (2008).
- (48) H. Wang, L. Zhou, and J. Gong, Interband coherence induced correction to adiabatic pumping in periodically driven systems, Phys. Rev. B 91, 085420 (2015).
- (49) L. Zhou, D. Y. Tan, and J. Gong, Effects of dephasing on quantum adiabatic pumping with nonequilibrium initial states, Phys. Rev. B 92, 245409 (2015).
- (50) See Supplemental Material for theoretical and experimental details.
- (51) In M. D. Schroer, et al, Phys. Rev. Lett. 113, 050402 (2014), this model was realized using a superconducting qubit. There, the system parameters were mapped differently onto the spherical angular coordinates of the spin Bloch sphere, and the band touching points can hence be seen as topological phase transition points because the first Chern number defined on a spherical manifold makes a jump there. The Chern number was measured by use of a generalized force in response to the time variation of .
- (52) M. W. Doherty, N. B. Manson, P. Delaney, F. Jelezko, J. Wrachtrup, L. C. L. Hollenberg, The nitrogen-vacancy colour centre in diamond, Phys. Rep. 528, 1 (2013).
- (53) R. Schirhagl, K. Chang, M. Loretz, and C. L. Degen, Nitrogen-Vacancy Centers in Diamond: Nanoscale Sensors for Physics and Biology, Annu. Rev. Phys. Chem. 65, 83 (2014).
- (54) S. Prawer and I. Aharonovich, Quantum Information Processing with Diamond (Woodhead Publishing, Cambridge, England, 2014).
- (55) J. Wrachtrup and A. Finkler, Single spin magnetic resonance, J. Magn. Reson. 269, 225 (2016).
- (56) V. Jacques, P. Neumann, J. Beck, M. Markham, D. Twitchen, J. Meijer, F. Kaiser, G. Balasubramanian, F. Jelezko, and J. Wrachtrup, Dynamic Polarization of Single Nuclear Spins by Optical Pumping of Nitrogen-Vacancy Color Centers in Diamond at Room Temperature, Phys. Rev. Lett. 102, 057403 (2009).
- (57) T. van der Sar, Z. H. Wang, M. S. Blok, H. Bernien, T. H. Taminiau, D. M. Toyli, D. A. Lidar, D. D. Awschalom, R. Hanson, and V. V. Dobrovitski, Decoherence-protected quantum gates for a hybrid solid-state spin register, Nature 484, 82 (2012).
- (58) L. Robledo, L. Childress, H. Bernien, B. Hensen, P. F. A. Alkemade, and R. Hanson, High-fidelity projective read-out of a solid-state spin quantum register, Nature 477, 574 (2011).
- (59) X. Rong, J. Geng, F. Shi, Y. Liu, K. Xu, W. Ma, F. Kong, Z. Jiang, Y. Wu, and J. Du, Experimental fault-tolerant universal quantum gates with solid-state spins under ambient conditions, Nat. Commun. 6, 8748 (2015).
The initial state prepared in the experiment for each is with