Evidence of delayed light emission of TetraPhenyl Butadiene excited by liquid Argon scintillation light

Evidence of delayed light emission of TetraPhenyl Butadiene excited by liquid Argon scintillation light

E. Segreto ettore.segreto@lngs.infn.it, segreto@ifi.unicamp.br Instituto de Fisica ”Gleb Wataghin” Universidade Estadual de Campinas - UNICAMP - Rua Sergio Buarque de Holanda, No 777, CEP 13083-859 Campinas, Sao Paulo, Brazil
Abstract

TetraPhenyl Butadiene is the wavelength shifter most widely used in combination with liquid Argon. The latter emits scintillation photons with a wavelength of 127 nm that need to be downshifted to be detected by photomultipliers with glass or quartz windows. TetraPhenyl Butadiene has been demonstrated to have an extremely high conversion efficiency, possibly higher than 100% for 127 nm photons, while there is no precise information about the time dependence of its emission. It is usually assumed to be exponentially decaying with a characteristic time of the order of one ns, as an extrapolation from measurements with exciting radiation in the near UV. This work shows that TetraPhenyl Butadiene, when excited by 127 nm photons, reemits photons not only with a very short decay time, but also with slower ones due to triplet states de-excitations. This fact can strongly contribute to clarify the anomalies in liquid Argon scintillation light reported in literature since seventies, namely the inconsistency in the measured values of the long decay time constant and the appearance of an intermediate component. Similar effects should be also expected when the TPB is used in combination with Helium and Neon, that emit scintillation photons with wavelengths shorter than 127 nm.

pacs:
29.40.Mc,33.50.Dq,33.80.Eh,61.25.Bi,78.47.jd

I Introduction

Liquid Argon (LAr) is a widely used active medium in particle detectors, especially in the fields of neutrino physics and Dark Matter direct search warp_100 (); icarus (); darkside (); micro (). It is often used in scintillation detectors thanks to its high photon yield ( 40000 photons/MeV at null electric field for m.i.p.) and to the possibility of discriminating different ionizing particles through pulse shape discrimination techniques (see for instance phd_rob ()). The wavelength of the emitted radiation is around 127 nm, so in the vacuum UV (VUV). The most efficient and viable way of detecting LAr scintillation light is to downshift it to longer wavelengths, where common quartz or glass windowed photo-devices are sensitive.
The most popular wavelength shifter used in combination with LAr is TetraPhenyl Butadiene (TPB) tpb_paper (); lally (); mckinsey (), that has been shown to have an extremely high efficiency in converting VUV photons into visible ones (possibly higher than 100 gehman ()).
On the other side there isn’t a precise knowledge of the TPB emission time spectrum when excited by 127 nm photons. It is usually described by a single decaying exponential with characteristic time in the range of 1 ns, as an extrapolation from measurements performed with exciting radiation in the range of the near UV (around 350 nm) flournoy (); camposeo ().
This is perfectly compatible with the photo-excitation of singlet states (S) of the electrons of the TPB molecules. They decay via internal conversion to the first excited singlet state S in less than one ns. The scintillation photon is produced by the radiative de-excitation of this state to the fundamental state (S S) that typically has a characteristic time of the order of one ns laustriat (); birks (); birks2 ().
The point never considered up to now is that VUV scintillation photons’ energy (9.7 eV) could very likely exceed the ionization potential of TPB. Actually there are no available data in the literature, but a calculation leads to a value of 5.4 eV kafer (). This could appear an extremely low energy, but it is worth noticing that similar compounds like p-terphenyl and anthracene, both used as scintillators or wavelength-shifters, have ionization energies between 7 and 8 eV, not so far from that estimated for TPB. Furthermore it is not difficult to find examples of conjugated molecules with response similar to that of TPB in the UV-vis region with ionization energies in the range of 5-6 eV, as PTCDA, Alq3 or CuPc hill ().
TPB molecules are very likely ionized by LAr scintillation photons and the emitted electron would have enough energy to excite singlet or triplet states of some of the surrounding molecules. Also the recombination of the electron-ion pair can lead to the population of triplet states. Excited singlet states produce the so called prompt fraction of scintillation within few ns through the de-excitation of the S states to the ground level. Excited triplet states decay very fast to the lowest lying triplet state T via internal conversion. These long lived states (the transition T S is forbidden by selection rules) are the precursors of the delayed fraction of the scintillation in pure aromatic media through the triplet-triplet interaction process: T + T S + S, where the scintillation photon is produced by the de-excitation of the S state laustriat ().
In this paper experimental evidence of the existence of a delayed component of the scintillation light of TPB excited by LAr VUV scintillation photons is presented. A similar effect has already been reported, for example, for sodium salycilate and for p-terphenyl (baker (); klein () and references therein).
This experimental fact can clarify some of the anomalies of LAr scintillation reported in literature. Namely the inconsistency in the measured values of the long decay time constant and the appearance of an unexpected intermediate component between the fast and the slow ones nitrogen (); lippincott (); heindl (); morikawa (). TPB ionization easily explains the observation of conversion efficiencies for LAr VUV photons higher that 100, since each absorbed photon could excite more than one TPB molecule at a time.

The same effect must also be present when TPB is used to downshift the scintillation light of liquid Neon and of liquid Helium, that are more energetic than LAr ones, since they have wavelengths around 80 nm. In particular it could have a role in explaining some of the not fully understood features in their time dependence.

Ii Experimental evidence

Measuring the time response of TPB at 127 nm is an extremely difficult task, because a fast pulsed 127 nm light source ( few ns FWHM) is required, together with a system that allows to drive VUV photons on a TPB layer. The experimental approach used in this work is based on the features of the LAr scintillation light itself and in particular profits of the fact that it can be reduced to a very fast pulse if the liquid is heavily contaminated by Nitrogen. The effects of Nitrogen contaminations on LAr scintillation light have been extensively studied in nitrogen () and the time response of TPB to 127 nm photons can be directly taken from there. In that work, in fact, the scintillation light, quenched by N, is wave-shifted by a TPB layer and then detected by a photomultiplier and at any level of N contamination studied, the probability density function in time (p.d.f.) of the photons has been measured. The p.d.f. at the highest concentration (3000 ppm) can be confidently interpreted as the time response of TPB to 127 nm photons. At that concentration, LAr scintillation is reduced to a pulse of the duration of few ns and consequently all the features observed in the p.d.f of the detected photons must be attributed to the time dependence of TPB fluorescence. It will be shown in section II.1 that it has a non trivial shape and that it contains a delayed component together with the expected prompt/instantaneous one.

In order to check that the p.d.f. measured with LAr VUV photons effectively represents the response of TPB and is not due to any side effect or uncontrolled systematics, like the unwanted pollution of the liquid by unknown contaminants, a dedicated experimental test has been performed. A TPB film has been directly irradiated with and particles and the p.d.f. of its scintillation light has been measured and compared with the one obtained with VUV photons in LAr.
The comparison allows to demonstrate that the delayed scintillation in the time response of the TPB to 127 photons is genuine and is a consequence of the triplet-triplet interaction process.

ii.1 TPB response to LAr scintillation photons

The scintillation light of LAr proceeds through the de-excitation of the excited dimer Ar and shows two decay components: one very fast ( 6 ns) originating from the decay of the lowest-lying singlet state - - and one very slow ( 1.3 s) from the decay of the lowest-lying triplet state - - kubota (); doke (). Sometimes an intermediate component with decay time of the order of 100 ns has been observed by experimental groups nitrogen (); lippincott (); morikawa (), not expected on the basis of the accepted theory of LAr scintillation mechanism.

It has been clearly shown nitrogen (); himi () that N contaminations in LAr produce a quenching of the scintillation light, while no other emission phenomenon from N has been observed even at extremely high levels of contaminations ( 10). The quenching process is a collisional one and the net effect is that the decay times of LAr scintillation components are shortened according to:

(1)

and consequently the relative abundances of the fast and slow components become:

(2)

where and are the decay times and amplitudes of the fast/slow component for uncontaminated LAr 111It is assumed here that the probability density function for scintillation photons is and , is the nitrogen contamination in ppm and is the reaction rate that has been measured to be nitrogen ().

Taking into account that for /e excitations of uncontaminated LAr, , , it can be easily found that for = 3000 ppm one obtains 2 ns, 3 ns, = 0.1 and = 1.4 10. In general any additional physical scintillation component of LAr would have a decay time below 3 ns.
The scintillation light in heavily N doped LAr results to be a very fast pulse that is ideal to study the TPB response to 127 nm photons.

In nitrogen () the results of a test of the effects of nitrogen contaminations in LAr are very clearly presented. The detector was constituted by a PTFE cell containing about 0.7 l of LAr lined up with a highly reflective foil (VM2000 by 3M) covered by a thin film of TPB (surface density gram/cm) and observed by a single 2” photomultiplier. An injection system allowed to contaminate the ultra pure LAr with controlled amounts of N. The details of the experimental set-up can be found in nitrogen (). Contamination levels ranging from 1 ppm to 3000 ppm of N were explored. For each different contamination the LAr cell was exposed to a source of Co. Scintillation light produced by electrons from interactions was wave-shifted on the surface of the cylinder and then detected by the photomultiplier. The average of the waveforms collected at 3000 ppm of N contamination is shown in figure 1 222This waveform is not shown in nitrogen (), but it has been kindly granted by the authors.. According to the previous discussion this waveform is obtained with a very fast 127 nm light excitation and it should be regarded as the time response of pure TPB to LAr scintillation photons.

Figure 1: (Color online) Response function of TPB for 127 nm photons at LAr temperature. It has been fitted with a function made of four decaying exponentials convoluted with a gaussian (see text). The result of the fit is represented by a red line.

This waveform clearly shows the expected very fast/instantaneous pulse, but also much slower components, that are interpreted here as coming from the triplet-triplet interaction process in TPB. It has been clearly demonstrated that the delayed scintillation of unitary organic scintillators is not exponential laustriat (); birks3 (); voltz1 (); voltz2 (), but to have a simplified quantitative idea of the time evolution of the emitted light the waveform has been fitted with a function made of four decaying exponentials, convoluted with a gaussian function that accounts for the photomultiplier response and for the electronic noise. A more adequate treatment of the delayed scintillation will be presented in section II.2. The result of the fit is shown in figure 1 with a red line and the abundance and decay time of the components are reported in table 1.

Figure 2: (Color online) Average waveforms for LAr scintillation light when excited by Co s at different levels of Nitrogen contamination: 0 ppm (a), 10 ppm (b), 20 ppm (c), 40 ppm (d). In red the results of the fits are shown. The fit function is a convolution of the TPB response function (3000 ppm average waveform) with the sum of two decaying exponentials, assumed to be the response of LAr.
decay time (nsec) abundance ()
Instantaneous component 1-10 60 1
Intermediate component 49 1 30 1
Long component 3550 8 1
Spurious component 309 10 2 1
Table 1: Decay times and relative abundances of the components found in the decomposition into exponentials of the response function of TPB to 127 nm photons. Only statistical errors from the fit are quoted.

Even if unphysical, the decomposition of TPB response into exponentials allows to put in evidence some useful features. The delayed scintillation of TPB accounts for about 40 of the total and it is necessary to integrate the waveform for at least 140 ns to accumulate the 90 of the signal. The slow part of the waveform fakes essentially two exponentially decaying components, one with a 50 ns slope, the most abundant, and one with 3.5 s.

Since during the N contamination test described in nitrogen (), data were taken for many different values of N concentration in LAr, a very stringent test of the hypothesis that the waveform shown in figure 1 represents the response of TPB to LAr scintillation photons has been possible. For each level of N the average waveform shown in nitrogen () has been fitted with a convolution of a double exponential, assumed to be the p.d.f. of LAr scintillation photons, with the response function of TPB. Some examples of fitted waveforms are shown in figure 2. In all the cases the fits are almost perfect and the average waveforms are reproduced very precisely along all the time interval considered (up to 9.7 s after the onset of the signal).
The picture that emerges from this analysis is perfectly consistent and there is no need of invoking exotic mechanisms of LAr scintillation, different from the two excimer states de-excitation ( and ), to explain all the features observed in the LAr scintillation waveforms. This is true in particular for one of the points deeply analyzed in nitrogen () without reaching definite conclusions, that is the existence of an intermediate decaying component between the singlet and triplet de-excitation.

ii.2 Test with and interactions

Following the idea that the waveform of figure 1 can represent the response of TPB to LAr scintillation photons, a dedicated experimental test has been performed. In order to check if the observed long tail is effectively related to TPB de-excitation, a sample of pure TPB has been directly irradiated with an ionizing radiation in a vacuum environment. This guarantees the formation of triplet states (through electron-ion recombination, secondary electrons excitations, -rays…), that are in turn the precursors of the delayed TPB scintillation, with a perfectly shaped excitation function and in a way completely independent from LAr scintillation light.

In general the scintillation of pure organic crystals excited by an ionizing radiation can be well described with the superposition of a prompt component and of a delayed one. The prompt component is found to be exponentially decaying with a time constant identical to the mean lifetime of the first excited singlet state S.
The time evolution of the delayed component depends on the dynamics of the triplet-triplet interaction process. It can be predicted by solving the diffusion-kinetic equation for the triplet density along the ionizing track, assuming a Gaussian shape, with scale parameter r, for the initial triplet distribution function laustriat (); voltz1 (); voltz2 (). The asymptotic time dependence of the delayed light (t) is found to be:

(3)

where N and A are constants depending on the nature of the scintillator, is the fluorescence yield and t is a relaxation time that is linked to the diffusion coefficient of triplet states in the scintillator, D, through the relation: t = r/4D.
The time evolution of the delayed light does not depend on the particle type, but only on the dynamics of the triplet-triplet interaction process. Only the relative abundance of fast and delayed components is expected to depend on the linear energy transfer, and consequently on the particle type.

The experimental set-up that has been built is essentially constituted by a stainless steel vacuum tight chamber that hosts a 2” photomultiplier (ETL D745UA), an holder for the TPB sample and one for the radioactive source. A schematic view of the set-up is shown in figure 3. The TPB sample is a film with a surface thickness 10 gram/cm evaporated on a highly reflective plastic foil (3M VM2000) circular in shape with a diameter of 8 cm. The choice of having a reflective substrate below the TPB has been done to maximize the amount of light that could be collected by the photomultiplier. A drawback of using VM2000 is that it is weakly emitting light when irradiated by ionizing particles. The film has been produced at LNGS with a dedicated evaporation system. More details can be found in aging (). The distance between the sample and the photomultiplier is 5 cm. Two sources have been alternatively used:

  • an source made of an alloy of Uranium and Aluminum that emits particles with a continuous spectrum with end point around 5 MeV;

  • a Sr source with a Q value of 546 keV.

Figure 3: (Color online) Scheme of the experimental set-up used to irradiate TPB films with electrons and particles.

During each measurement the stainless steel chamber has been evacuated down to a pressure of 510 mbar to allow particles and electrons to hit the TPB film without being captured by air. Scintillation signals detected by the photomultiplier have been sent to a fast Waveform Recorder (Acqiris, DP235 Dual-Channel PCI Digitizer Card). The signal waveforms passing a threshold set at a level corresponding to few photo-electrons have been recorded with sampling time of 1 ns over a full record length of 10 s.
All the measurements have been performed at room temperature, since it has been shown in veloce () that the time dependence of the late components of TPB fluorescence excited by particles does not change appreciably at LAr temperature.

ii.3 Data analysis and comparison

The average waveforms for the and particles tests have been calculated applying simple cuts to eliminate waveforms that present saturations, afterpulses or multiple signals and the result is shown in figure 4.
The red curve refers to irradiation and the blue one to , while the black curve is the one obtained with LAr scintillation light, already shown in figure 1, reported here for visual comparison. Beta and VUV photons curves are nicely overlapped as is observed also for sodium salicylate baker (). The small differences found around 300-400 ns after the onset of the signal could be ascribed to a small effect of fluorescence of the plastic substrate of the TPB film, since the electrons have enough energy to reach and traverse it. particles, instead, show a much higher abundance of delayed component.

Figure 4: (Color online) Red line: average waveform obtained by irradiating a TPB film with electrons. Blu line: average waveform obtained by irradiating a TPB film with particles. Black line: average waveform obtained irradiating TPB with LAr scintillation light quenched by 3000 ppm of Nitrogen.

In order to investigate the details of the tails of the three curves and to check if they are compatible with each other a single photon counting like procedure has been adopted. The classical Coincidence Single Photo-electron Counting technique has been used many times in scintillation lifetime measurements himi (); hitachi (); carvalho (). The recorded waveforms allow to implement an offline version of this technique. Starting at 170 ns after the onset of a triggered signal, a single photo-electron finding algorithm is run through the waveform and for each photo-electron pulse (defined by appropriate cuts) the arrival time is stored. In order to minimize the pile-up of single photo-electrons, that is a time dependent effect, only waveforms with a total integral below 40 photo-electrons in the case of electron and photon excitations and 20 in the case of s are considered. In this way the pile up probability in the first 30 ns results to be below 5 in all three cases.

Figure 5: (Color online) Normalized histograms of the arrival time of single photons for photon (black curve), (red curve) and electron (green curve) excitations of TPB.

The time of arrival of photo-electrons have been accumulated in three histograms, that are shown in figure 5. They are almost perfectly overlapped. The histogram related to VUV photons has also been fitted with the function of equation 3 where A, t and the product N are left as free parameters. The result of the fit is shown in figure 6 with a blue line. The best fit values for A and t are 0.22 and 51 ns respectively, not so different from what is found for anthracene bollinger () - A=0.25 and t=40 ns - and for stilbene wasson () - A=0.25 and t=80 ns.

Figure 6: (Color online) Histogram of arrival times of single photons for TPB excited by VUV photons. The blue line represents the result of the fit with the function of equation 3.

The perfect compatibility of the delayed scintillation of TPB excited by LAr scintillation photons with that induced by ionizing particles clearly demonstrates that it is generated by a triplet-triplet interaction mechanism, started by the ionization of TPB by 127 nm photons. The TPB response function to LAr scintillation light is not a fast decaying exponential, as it is found for near UV excitation, but has a much more complex structure with a delayed component that has a non-exponential shape and that accounts for about the 40 of the emitted radiation.

Iii Discussion

The waveform shown in figure 1 confidently represents the response function in time of TPB to 127 nm. Having demonstrated that convoluting it with the sum of only two exponentially decaying functions allows to reproduce the average waveforms measured at any level of contamination is a remarkable point. It demonstrates that the time evolution of LAr scintillation light can be described as the sum of only two decaying exponentials, originated from the de-excitation of the lowest lying triplet and singlet states of the Ar excimer. The observation of an intermediate component with a decay slope in the range of 50-100 ns often reported in literature nitrogen (); lippincott (); amsler () can be totally ascribed to the fluorescence of TPB. It is the slow TPB de-excitation following the fast LAr scintillation pulse. It has been shown in section II.1, in fact, that the TPB response function fakes a 50 ns component, if one attempts to decompose it into exponentials. Also the difficulty of determining unambiguously the slope of the slow scintillation component of LAr can be a consequence of the use of TPB or of wavelength shifters in general. The long tail in the TPB response function, resembling a 3.5 s exponential, distorts the slow component of LAr scintillation photons and consequently any technique to measure its decay constant brings inside a certain amount of uncontrolled systematics if the effect of TPB is not properly deconvolved. It has been shown in nitrogen (), for example, that the use of two slightly different fitting procedures lead to two quite different values of the LAr slow decay slope. In this respect the most reliable value appears to be the one of 1300 60 ns reported in heindl (), measured without shifter, and in nitrogen () with sophisticated deconvolution techniques.

LAr is used in several experiments for the direct Dark Matter detection mainly because it allows to reject efficiently and background with respect to nuclear recoil events that could be due to a WIMP (Weakly Interactive Massive Particle) signal warp_100 (); darkside (); ardm (); deap () . In fact different ionizing particles produce very different scintillation signals in LAr. In particular the relative abundance of the fast to slow scintillation components are different for electrons, s and nuclear recoils, being respectively 1/3, 1.3 and 3 hitachi (); lippincott (); phd_rob (). The most widely used technique to exploit the pulse shape discrimination of LAr is based on the calculation of the prompt fraction of light in the signals. A factor, usually called F, is defined as follows:

(4)

where I(t) is the intensity of the detected scintillation signal measured in photo-electrons and t is the integration time of the prompt signal that maximizes the separation among different particles . It has been found experimentally by many groups that the optimum value of t is around 100 ns warp_100 (); darkside (); lippincott (); phd_rob (). This an indirect but clear confirmation of the existence of the delayed fluorescence of TPB.
According to the picture that emerges from this work, the scintillation of LAr shifted by TPB can be described by the p.d.f. :

(5)

where S(t) and T(t) are the fast and slow exponential components of LAr both convoluted with the TPB response and A is the fraction of prompt light. It is straightforward to prove that t can be found by solving the equation:

(6)

The graphical solution of equation 6 is shown in figure 7 and leads to a value of t around 120 ns, perfectly compatible with the experimental observations333in this case, for simplicity, it has been used the representation of the TPB response function in terms of exponentials. .

Figure 7: (Color online) Graphical solution of equation 6. In black the function S(t) and in red T(t). The solution is represented by the crossing point of the two functions, that is found around 120 ns.

If the delayed scintillation of TPB were not present, S(t) and T(t) could be described by two exponentials, with characteristic times of 6 ns and 1300 ns, that is:

(7)

In this case equation 6 could be analytically solved and, in the limit of , one obtains:

(8)

that returns a value for t around 32 ns, three times lower than its experimental value.
The delayed fluorescence of TPB has also the effect of deteriorating the discrimination capability of LAr that could be obtained in the ideal case of a direct detection of the VUV photons. This is because a fraction of the prompt light is delayed and the two LAr scintillation components are more mixed. A rough calculation can be very explicative. Without the shifter, the average value of F for electrons and neutrons can be easily calculated. Assuming a fraction A for the prompt scintillation of electrons and neutrons of 0.25 and 0.75 respectively and considering a value of t of 32 ns, simple exponential integrations of equation 7 leads to F values of 0.27 and 0.75 with a difference = 0.48. In the usual situation, that is with TPB, a numerical integration of the p.d.f. of equation 5 up to t = 110 ns leads to F values of 0.27 and 0.67 for electrons and neutrons respectively with a difference of = 0.4. The use of the shifter worsens the separation between electrons and neutrons of about 17.

TPB is widely used also to downshift the scintillation photons of liquid Helium (LHe) and Neon (LNe) lippi_neon (); mc_he (), that have energies higher than that of LAr ones. This suggests that the same mechanism of TPB delayed fluorescence should be active also in these cases. Despite the fact that it was never explicitly noticed, it could be useful in explaining some of the not fully clarified features of LNe and LHe scintillation. It has been shown in mc_he () that the scintillation of LHe has a non-trivial time structure. In addition to the expected fast and slow components originated by the de-excitation of the lowest lying triplet and singlet states of the excimer He, with decay times of 10 s and 10 ns respectively, two more components are observed, one exponential with a characteristic time of 1.6 s and one non exponential that decays as . The delayed scintillation of TPB could represent a non negligible contribution to these scintillation components since it is active exactly in the same time range. Even if a direct and quantitative comparison is not reasonable, due to possible effects related to the large difference in temperature, the component resembles the asymptotic behavior of the TPB response function measured in LAr. On the other side the experimental evidence that the 1.6 s exponential decay is different for cold Helium gas than for LHe mc_he () demonstrates that some additional process must be active inside the LHe and the observed features can not be completely explained by the delayed TPB fluorescence.

A similar situation is found for LNe scintillation, where two approximately exponential intermediate components between the singlet and triplet Ne de-excitations are found lippi_neon (), with characteristic times in the range of 100 ns and 1 s. Their origin is not clear, but it is plausible that TPB delayed scintillation can contribute to explain at least a fraction of it.

Iv Conclusions

This work shows the experimental evidence of the existence of a delayed scintillation component of TPB when excited by the VUV radiation of LAr. The production of the triplet states, that are the precursors of the delayed light, is made possible by the high energy of LAr scintillation photons that can ionize the organic molecules of TPB. Its time dependence has been measured with an experimental set-up that uses LAr scintillation light quenched by nitrogen contaminations to excite TPB. It has been compared to the time behavior of the delayed light of TPB when excited by and particles and they have been found to be perfectly compatible among each other. The time shape of the light emission has also been found to be consistent with what expected from the delayed luminescence of a unitary scintillator as described in literature.

This experimental fact sheds some light on the most relevant incongruities that have been reported in the past years concerning the time dependence of LAr scintillation light. Namely the presence of an intermediate component with a decay time in the range of 50-100 ns and the ambiguity in the determination of the decay time of the slow component, for which values ranging from 800 ns to 1600 ns have been reported.

LAr scintillation is often used for particle discrimination since the relative abundance of the fast and slow components strongly depends on the particle type. The use of TPB tends to worsen this feature of LAr since a consistent part of the prompt light is delayed and the two populations are more mixed.
TPB is an exceptionally efficient shifter for the VUV scintillation light of LAr and also a convenient one for its emission wavelength around 430 nm matching the quantum efficiency of many standard photomultipliers, but it has some drawbacks when the time features of the scintillation signals are used since they result to be slightly distorted.

V acknowledgments

The author acknowledges Prof. F. Cavanna for his contribution to this work with discussions and ideas; Prof. R. Francini for the discussions on molecular processes; Dr. A. A. Machado for her help and patience and Dr. N. Canci for his contribution to the measurements with and particles.
This paper is dedicated to the memory of Antonio Di Filippo.

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