Equilibrium shapes of charged droplets and related problems: (mostly) a review
Abstract.
We review some recent results on the equilibrium shapes of charged liquid drops. We show that the natural variational model is illposed and how this can be overcome by either restricting the class of competitors or by adding penalizations in the functional. The original contribution of this note is twofold. First, we prove existence of an optimal distribution of charge for a conducting drop subject to an external electric field. Second, we prove that there exists no optimal conducting drop in this setting.
The main purpose of the paper is to review some recent progress in the study of variational problems describing the shape of conducting
liquid drops. The salient feature of these models is the competition between an interfacial term with a nonlocal and repulsive term of capacitary type.
The somewhat surprising and puzzling fact is that contrarily to the experimental observations these models are generally illposed.
However, taking into account various possible regularizing mechanisms it
is possible in some cases to recover wellposedness together with stability results for the ball in the regime of small charges.
Alongside this review, we also provide new results on the closely related problem of equilibrium shapes of conducting drops subject to an external electric field.
We prove that for every fixed drop, the optimal distribution of charges exists but that as for the charged drops model, no equilibrium shape exists. Moreover, we show that wellposedness cannot be recover easily since minimizer do not exist even in the rigid class of convex sets.
The paper is organized as follows. In Section 1 we recall the definition of the capacity and study existence and characterization of optimal distributions of charges. In Section 2 we review some recent results on the charged liquid drop model. In particular, we show illposedness of this problem and discuss various possible regularizations. In Section 3 we study the problem of equilibrium shapes for perfectly conducting drops in an external electric field. In the last section, we state several open problems.
1. Equilibrium measures, potentials and capacities
We start by investigating the optimal distribution of charges for a given compact set . Most of the results can be found in [Lan72, GNR15, GNR16]. For fixed , and Radon measures , we define
and let then . With a slight abuse of notation, we also let
The equilibrium measure of a set is the solution of the problem
where the class of minimization runs over all probability measures on . We denote by the Riesz potential energy of . We can then define the capacity of a set as
For a given measure , it is useful to define the associated potential
and its natural counterpart in the logarithmic case . We list below some known facts about equilibrium measures and potentials.
Theorem 1.1.
Let be a compact subset of and be such that ^{1}^{1}1this is for instance the case if is a compact set with .. Then,

There exists a unique equilibrium measure [Lan72, p. 131–133].

There exists a constant such that the potential satisfies
in the distributional sense (here refers to the Laplacian). In particular is harmonic outside of the support of . Moreover q.e. on the support of ^{2}^{2}2we say that a property holds q.e. if it holds up to a set of zero capacity. and q.e. on [GNR15, Lem. 2.11].

For ,
while for ,

For , the support of coincides with [GNR15, Lem. 2.15].

For the support of is contained in and on [GNR15, Lem. 2.15].
Remark 1.2.
In the claim of point of the previous theorem the support of is not equal to in general. For example, if is the circular annulus
then its optimal measure for is equal to the equilibrium measure of the ball that is
Remark 1.3.
Remark 1.4.
For and one can show that the (fractional) capacity of a set can be characterized as
Notice that for , reduces to the Dirichlet energy of .
Remark 1.5.
As pointed out in [GNR16], in the Coulombic case , the equilibrium measure coincides with the socalled harmonic measure at infinity of .
The next result gives a link between sets of Hausdorff dimension at least and sets of positive capacity (see [Lan72, Th. 3.13]).
Proposition 1.6.
Let . Then if the Hausdorff dimension of is greater than , .
We now study the existence of an equilibrium measure for a conducting set subject to an external electric field . We focus on the Coulombic case and . For a (signed) measure supported on with , the electrostatic energy of is given by
while the electrostatic energy of is
(1.1) 
Let us notice that in contrast with the situation of Theorem 1.1, the existence of minimizers for (1.1) is not straightforward. Indeed, a bound on does not give a bound on the total variation of (see for instance [Lan72, Chap. VI]).
This prevents us from using the Direct Method of Calculus of Variations. Instead we will directly look for a solution of the EulerLagrange equation and prove that it is a minimizer of (1.1).
We start by recalling that [Lan72, Th. 1.15]
Proposition 1.7.
For every signed measure , and if and only if .
The next proposition shows that solutions of the EulerLagrange equation are minimizers.
Proposition 1.8.
Proof.
Assume that and exists and let . To show that is optimal, we notice that if is another measure with , then
Integrating the equation against in and using that , we get that
Using Proposition 1.7 we conclude the proof.∎
We are thus left with the construction of a constant and a function satisfying the hypothesis of Proposition 1.8. In order to avoid technicalities, we will assume that and are smooth. For later use, let be the solution of
which can be readily constructed from the measure which minimizes .
Proposition 1.9.
For , let be a smooth compact set and let be a smooth function on . Then, there exists a unique solution of
(1.3) 
Moreover, is a bounded measure on .
Proof.
The uniqueness part of the statement follows by maximum principle. Let us turn to the existence. For , let be the unique solution of
Let and and let . By maximum principle, . Since at infinity, using elliptic regularity and letting
we obtain a function which satisfies (1.3).
To see that is a measure it is enough to notice that for , we have
where is the outward normal to and where is the exterior trace of . ∎
We can now prove our main result of this section.
Theorem 1.10.
For every smooth compact set and every smooth function there exists a unique solution to (1.1).
2. Equilibrium shapes of charged liquid drops
The study of the equilibrium shapes of charged liquid drops started with the seminal paper of Lord Rayleigh [Ray82] who calculated through a linear stability analysis
the maximal charge that a spherical drop can bear before the onset of instability. It was later observed by Zeleny [Zel17] that for larger charges, conical singularities (the socalled Taylor cones) appear together with the formation of a thin steady jet.
Since then it has been understood that the microdrops forming the jet carry a large portion of the charge but only a small portion of the mass (see [FdlM07]).
Because of its numerous applications in particular in mass spectrometry [Gas97], this phenomenon has attracted a wide interest in the last thirty years. We refer to [MN16] for a more detailed discussion on the physical background and literature.
Let us point out that mathematically, very little is known about what happens after the onset of singularities. In particular the formation of the Taylor cones is still badly understood (see [FJ15, GVW16] for some results in this direction).
The variational model describing the equilibrium shape of a charged liquid drop is the following. For a given charge the energy of a compact set is equal to
where refers to the dimensional Hausdorff measure. Up to a renormalization of the volume, we are looking for a solution of
(2.1) 
The physical case corresponds to , with Coulombic interaction . When the charge distribution is taken to be uniform on , this problem is often called the sharp interface OhtaKawasaki model (or Gamow’s liquid drop model). See [CMT17] for a recent overview of this related problem.
The mathematical interest of (2.1) lies in the fact that there is a competition between the perimeter which is a local term minimized by the ball and the nonlocal electrostatic energy which is maximized by the ball (at least for [Bet04]). Based on the experimental observations, the linear stability analysis (see in particular [Ray82, FF04]) and by analogy with what is known for the OhtaKawasaki model,
one could expect that for small the ball minimizes (2.1) while for large no global minimizers exist. Surprisingly enough, this is not the case and the problem is always illposed when . Roughly speaking this is due to the fact
that the perimeter term sees objects of dimension while naturally lives on object of dimension , see Proposition 1.6. The following nonexistence result has been obtained in [GNR15, Th. 3.2].
Theorem 2.1.
Proof.
For and , let . Consider the competitor made of balls of radius each carrying a charge and infinitely far apart together with a ball of radius which is free of charge. We can then compute the energy
By the choice of ,
which concludes the proof. ∎
Performing a more careful analysis it can be shown that actually even local minimizers do not exist for the Hausdorff topology (see [GNR15, Th. 3.4]). If the construction leading to the nonlinear instability of the ball described here is made of many disconnected components, it has been proven in [MN16, Th. 2] that (at least in the physical case , ) the ball is actually unstable even in the class of smooth graphs over the ball.
Theorem 2.2.
Let and . Then, for every , there exists a smooth function such that letting
we have and
In the case one can expect a stronger interaction between both terms in (2.1) which might restore wellposedness. This has been recently investigated in [MNR16] in the case , , which corresponds to three dimensional drops trapped between two very close isolating plates. The authors were able to completely solve this problem
Theorem 2.3.
Let and . There exists an explicit such that for , the only minimizer of (2.1) is given by the unit disk while for , there are no minimizers.
Proof.
A rough idea of the proof is the following: the crucial observation is that in dimension two, the energy of a connected set decreases under convexification. Of course this operation does not preserves the volume. This motivates dropping the volume constraint and studying the global minimizer of the energy. By the above observation, a global minimizer is made of a union of convex sets. Using the linearity (respectively the sublinearity) of the perimeter (respectively of the Riesz capacity) with respect to the Minkowski sum, it can be shown that the ball is the global minimizer of the energy amongst convex sets. The global minimizer is thus made of a union of balls from which it is readily seen that it is actually a single ball. Therefore, for any radius there exists a charge such that the ball of radius is the only minimizer (up to translation) of
Here we adopted the notation instead of just to emphasize the dependence on the charge. Let be the charge associated to . If , then using a construction similar to the one used in the proof Theorem 2.1, it is possible to prove nonexistence of a minimizer while for , since for every with ,
with equality if and only if , we obtain that the ball is the unique solution of (2.1). Notice that in the second inequality we used that the ball is a maximizer of under volume constraint. ∎
Turning back to the case where (2.1) is illposed, it is natural to wonder if restricting the admissible set could restore wellposedness. A first possibility, explored in [GNR15] is to add a strong constraint on the curvature. For , we say that a set satisfies the ball condition if for every there are two balls of radius touching at , one of which is contained in and the other one which is contained in . Notice that this implies in particular that is with all the curvatures bounded by . We set
Under this regularity assumption, it was proven in [GNR15, Th. 4.3] that minimizers exist for small enough charges while nonexistence for large charges holds in the case [GNR15, Th. 4.5].
Proposition 2.4.
For every and , there exists such that for every small enough and every a minimizer of
(2.2) 
exists. Moreover, if , there exists such that for every small enough and every , no minimizer of (2.2) exists.
Proof.
For the existence part the main point is to prove that every minimizing sequence must be connected for . By (almost) minimality, we have
(2.3) 
The quantitative isoperimetric inequality [FMP08] then implies that . Thanks to the ball condition, this yields that is indeed connected for .
The nonexistence part is obtained by constructing a competitor made of balls of radius .
∎
In the Coulombic case , it was shown in [GNR15, Th. 5.6] (see also [GNR15, Cor. 6.4] for the logarithmic case when ) that for small enough charges, the ball is the unique minimizer of (2.2).
Theorem 2.5.
Let and . Then there exists such that for , is the only minimizer (up to translation) of problem (2.2).
The proof of this result is quite long and involved but the basic idea is to argue as in [CL12, KM14, FFM15, GM17] for instance and show that for small charges minimizers are nearly spherical sets, that is small Lipschitz graphs over . This allows the use of a Taylor expansion of the perimeter for this type of sets given by Fuglede [Fug89]. The main technical lemma is the following (see [GNR15, Prop. 5.5] and the proof of [GNR15, Th. 5.6]).
Lemma 2.6.
For and , if is a nearly spherical set and if the optimal measure is bounded in , then there exists a constant depending on this bound such that
(2.4) 
Thanks to the ball condition, it can be proven that for small enough, minimizers of (2.2) satisfy the hypothesis of Lemma 2.6. The proof of Theorem 2.5 is concluded by combining (2.4) together with (2.3).
Remark 2.7.
An alternative way to restore wellposedness for (2.1) is to reduce the admissible class to convex sets. If this geometric restriction is not directly comparable with the ball condition, it allows for less regular competitor (Lipschitz). As shown in [GNR16, Th. 2.3], under the convexity constraint, there is always a minimizer for (2.1).
Theorem 2.8.
For every , and , there exists a minimizer of
(2.5) 
Having Theorem 2.5 in mind, it is natural to wonder if, at least in the Coulombic case, (2.5) is still minimized by the unit ball for small . In the bidimensional logarithmic case, it has been proven to hold in [GNR16, Th. 5.1].
Theorem 2.9.
Let then for small enough, the only minimizer of (2.5) is the unit ball.
The idea is to show that for small charges, minimizers of (2.5) satisfy the hypothesis of Lemma 2.6. This is a consequence of the following regularity result [GNR16, Th. 4.4] .
Theorem 2.10.
For and every , every minimizer of (2.5) is , with uniform bounds for small .
This result proves that in dimension two and when restricted to the class of convex sets, conical singularities never appear. The proof of Theorem 2.10 is quite long and technical
but the main idea is to show that if is not regular enough, then we can lower the energy by replacing part of the boundary by a straight line. The major difficulty is to precisely estimate the variation of the nonlocal term.
A crucial technical point is that for convex sets, the optimal charge distribution is in for some (see [GNR16, Th. 3.1]). In higher dimensions, it seems difficult to obtain regularity by such simple cuttingbyplanes argument but it would be interesting to investigate further this question.
Instead of imposing constraints on the admissible sets, another way of restoring wellposedness is to take into account regularizing mechanisms in the functional. One possibility, proposed in [MN16] is to take into consideration entropic effects and impose that the charge is distributed in . The functional then becomes (in the physical case , )
where
We refer to [MN16] for a physical motivation of this model. Their main result is existence of minimizers for this functional (see [MN16, Th. 3]).
Theorem 2.11.
For every and every , there exists a minimizer of
Not much is known at the moment about the regularity of the minimizers of this problem. The stability of the ball is also an open question.
3. A perfectly conducting drop in a uniform external field
The problem of finding the equilibrium shape of charged droplets is closely related to the problem of finding the equilibrium shape of a conducting drop submitted to an external electric field. If the understanding of meteorological phenomena has first motivated the study of this question [WT25], the wide spectrum of modern applications ranging from the breakdown of dielectrics due to the presence of water droplets to inkjet printers might explain the large amount of literature on the subject (see for instance [Mik81, DM07, KDT14]). In the simplest and most considered case of a constant external field , we have (recall (1.1)) for with ,
and we look for a minimizer of
(3.1) 
It is quite easy to see that this problem is illposed.
Theorem 3.1.
For every , and every ,
Proof.
Without loss of generality, we may assume that . Consider for the admissible set made of two disjoint balls of measure and centers . We then have
Using as test measure for , we find
which goes to as . ∎
Contrarily to the case of charged liquid drops, illposedness still holds in the class of convex sets.
Theorem 3.2.
For every and every ,
Proof.
As before, we may assume that . For , consider the set
where
Notice that is chosen so that . By definition of we have
Moreover, by letting
and then
we have that is admissible for and thus . Since on the one hand,
and on the other hand
we find that
which diverges to as . ∎
4. Open problems
In this last section we state few open problems.

As already pointed out, in light of the large physical literature about the Taylor cones, it would be interesting to find a reasonable setting where these can be rigorously studied.

A first step would be for instance to understand if Theorem 2.9 still holds in dimension or if conical singularities can appear in the class of convex sets.

It is still an open question to know if the ball is stable under small Lipschitz deformations for small charges.

It is natural to try to extend the stability analysis for the ball to .

In light of Theorem 2.5, it would be interesting to see if wellposedness holds (for small charge) when .

Not much is known about the minimizers of the functional introduced in [MN16]. It would be interesting to study existence/nonexistence of minimizers without confinement, their regularity and the stability of the ball.

Another natural way to regularize (2.1) would be to add a curvature term of Willmore type in the energy. One would then study the functional
where is the mean curvature of .

The physical model behind the electrowetting technique is very similar to the ones studied here. This technique, which is used for optical devices and electronic displays consists in applying a voltage on a sessile conducting drop. As already observed by Lippmann [Lip75] in 1875, this leads to a modification of the (apparent) contact angle, while the microscopic contact angle is still the one given by the classical Young law [SW09]. It was discovered later on that the macroscopic angle decreases until reaching a saturation angle (see the review paper [MB05]). Despite its importance for application, there has been only few rigorous results about electrowetting (see [FK09, FK08]) and it would be interesting to study both the formation of the macroscopic angle and the saturation phenomenon.
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