Electro-absorption of silicene and bilayer graphene quantum dots

Electro-absorption of silicene and bilayer graphene quantum dots

Hazem Abdelsalam hazem.abdelsalam@etu.u-picardie.fr University of Picardie, Laboratory of Condensed Matter Physics, Amiens, 80039, France Department of Theoretical Physics, National Research Center, Cairo,12622, Egypt    Mohamed H. Talaat Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt    Igor Lukyanchuk University of Picardie, Laboratory of Condensed Matter Physics, Amiens, 80039, France L. D. Landau Institute for Theoretical Physics, Moscow, Russia    M. E. Portnoi School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL, United Kingdom    V. A. Saroka v.saroka@exeter.ac.uk School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL, United Kingdom Institute for Nuclear Problems, Belarusian State University, Bobruiskaya 11, 220030 Minsk, Belarus
July 13, 2019
Abstract

We study numerically the optical properties of low-buckled silicene and AB-stacked bilayer graphene quantum dots subjected to an external electric field, which is normal to their surface. Within the tight-binding model, the optical absorption is calculated for quantum dots, of triangular and hexagonal shapes, with zigzag and armchair edge terminations. We show that in triangular silicene clusters with zigzag edges a rich and widely tunable infrared absorption peak structure originates from transitions involving zero energy states. The edge of absorption in silicene quantum dots undergoes red shift in the external electric field for triangular clusters, whereas blue shift takes place for hexagonal ones. In small clusters of bilayer graphene with zigzag edges the edge of absorption undergoes blue/red shift for triangular/hexagonal geometry. In armchair clusters of silicene blue shift of the absorption edge takes place for both cluster shapes, while red shift is inherent for both shapes of the bilayer graphene quantum dots.

Electro-absorption; optical properties; silicene; bilayer graphene; quantum dots; electric field
pacs:
81.07.Ta, 78.67.Wj

I Introduction

Non-planar graphene-derivative materials have attracted considerable attention Ni2014 (); Tsai2013 (); Kumar2011 (); Liang2012 (); Artyukhov2010 (); Lui2011 (); Lukyanchuk (); Ezawa2015 () because of their tunable electronic properties, different from those of the single-layer graphene. Application of the electric field, , across the bilayer (multilayer) graphene system opens a gap between the conduction and valence bands. McCann (); ECastro2007 (); Ohta2006 (); Khodkov2015 () The same also happens with silicene because of the buckling of its honeycomb lattice.Tsai2013 (); Kumar2011 (); Liang2012 (); Lui2011 () The atoms of the type A and B of the lattice are displaced alternatively in the vertical direction and are subjected to a different, electric field producing, potential gradient. The possibility of controlling the gap offers a wealth of new routes for the next generation of field effect transistors and optoelectronic devices.Ni2014 (); Tsai2013 (); koshino2013 () However, the on-chip nano-scale realization of such devices requires finite-size components like nanoribbons and nanoflakes or quantum dots (QDs).Kvashnin2015 () Therefore, a deeper understanding of their individual electronic properties, which can be substantially different from those in infinite systems because of the finite-size electronic confinement,Sorokin2008 () is needed.

The electronic properties of various graphene nanoribbon structures and the influence of the applied voltage is being studied both for the out-of-planeSahu2008 (); Sahu2010 (); Yu2013 () and for the in-plane Huang2008 (); Chang2006 (); Saroka2014 (); Saroka2015 () field directions. The optical and magnetic properties of the single and multilayer graphene QDs of various shapes have also been studied at zero field.Ezawa (); Zhang2008 (); Chernozatonskii2013 (); Rossier2007 (); Potasz (); Kosimov (); Espinosa (); Espinosa2 (); Hazem (); Guclu2016 (); Zarenia2011 (); Costa2014 () The distinctive property of these QDs is the opening of a finite-size energy gap due to the electron confinement, that is different from the above mentioned field-induced gap since it exists also at . In addition, the novel electronic states localized at the sample boundary are formed.Ezawa (); Zhang2008 (); Rossier2007 () In the energy spectrum these states are located inside the gap in the vicinity of the zero energy. This corresponds to the Dirac point, when size of the system tends to infinity, therefore they are usually referred to as zero energy states (ZES). Unlike the ZES in single layer graphene QDs, the ZES in silicene and bilayer graphene QDs can be easily manipulated by an electric field applied normally to the graphene or silicene layers.Guclu2011 (); Hazem2 (); Costa2015 (); Costa2016 ()

In this paper we explore this functionality for the design of the QD-based optoelectronic devices. We discuss the effect of an electric field on the optical absorption cross section in silicene and bilayer graphene QDs and how the applied field can control the number and intensities of absorption peaks.

This paper is organized as follows: in Section II we introduce structure classification and provide details of our tight-binding calculations. In Section III we present and discuss optical absorption spectra in electric field for a range of QD types. Finally, our discussion is summarised in Section IV.

Ii Structures and calculation model

In this study we use a classification similar to that proposed for single layer graphene QDs. Zarenia2011 () The structures are classified based on their shape and edge type. As can be seen from Fig. 1, four types of QD can be distinguished. Depending on their edge geometry, QDs can be classified as the zigzag or armchair QDs that are presented in Fig. 1 (a), (b) and (c), (d), correspondingly. A quantum dot of each of these types can have triangular (TRI) or hexagonal (HEX) shape. The number of atoms in the cluster varies depending on its shape and size. Table 1 summarizes how different size characteristics are connected with the total number of atoms in the single layer structure, , by means of the number of characteristic hexagonal elements and the lattice parameter . The choice of a characteristic element for the structure indexing is a matter of convention. As shown in Fig. 1 by larger and smaller font numbering, one can count hexagons or, equivalently, edge atoms. In the case of a QD with zigzag edges, shown in Fig. 1 (a), (b), edge atoms on a single edge are counted, whereas for QDs with armchair edges, presented in Fig. 1 (c), (d), edge atom pairs are counted. Yamamoto2006 () The lattice parameter is the distance between the nearest atoms, or their projections onto a horizontal plane as depicted in Fig. 2 (d) and (b) for a flat and low-buckled structure, respectively. Apparently, to obtain the total number of atoms, , in a bilayer (multilayer) structure the number of atoms in the Table 1 should be multiplied by the number of layers.

(a)
(b)
(c)
(d)
Figure 1: The four main types of QD, based on the 2D hexagonal lattice: (a) zigzag triangular, (b) zigzag hexagonal, (c) armchair triangular , (d) armchair hexagonal, where and are the circumscribed circle radius and edge length, respectively. Quantum dot indexing is presented by larger and smaller font numbering.
Quantum dot type
Zigzag Armchair
triangular hexagonal triangular hexagonal
 111Ref. Zarenia2011 ()  1
 222Ref. Yamamoto2006 ()  2
Table 1: Relations between the number of atoms per layer, , and quantum dot size characteristics: circumscribed circle radius , edge length , and the number of edge atoms (or edge atom pairs ). The parameter is the distance between the nearest atoms in 2D hexagonal lattice or their projection onto a horizontal plane in case of the buckled structure ( Å for graphene and  Å for silicene Cahangirov2009 ()).

The electronic properties of presented clusters in a transverse electric field can be calculated using the tight-binding HamiltonianMcCann (); CLiu2011_2 (); Ezawa2012 (),

(1)

where and are the electron creation and annihilation operators, are the inter-site hopping parameters and is the on-site electron potential that depends both on the local atomic environment and on the applied electric field. The hoping parameters can be written in terms of the nearest-neighbor (NN) coupling constants , as illustrated in Fig. 2.

(a) Top view
(b) Top view
(c) Side view
(d) Side view
Figure 2: The structure and tight-binding hopping parameters for silicene (a), (c) and bilayer graphene (b), (d). In each case a black vertical arrow shows the direction of the applied electric field.

In the case of silicene we use the simplified version appropriate for the low-energy states.Ezawa (); CLiu2011_2 () According to this approximation there is only one in-plane coupling parameter between sites A and B, , that corresponds to the nearest-neighbor hopping between sites A and B.

For graphene this parameter is . The on-site potential, is different for A and B sites and can be presented as where for the B and A type of atoms, is the effective buckling-gap parameter and is the field-induced electrostatic interaction, related to the up/down shift of B and A atoms on with respect to the average plane.

For the bilayer graphene structure, along with the in-plane coupling , the inter-layer parameters , and ( see Fig. 2 (b)) should be also taken into account. The field-dependent on-site potential can be written McCann () as where for A1 and B2 atoms, for A2 and B1 atoms and for the atoms located in the upper (A2, B2) and lower (A1, B1) layers correspondingly (See Fig. 2). The on-site potential due to the different local atomic environments is taken as and the inter-layer distance as .

By numerically diagonalizing the Hamiltonian given by Eq. (1) one finds the single-electron wave functions and their corresponding energy levels , which can then be used to evaluate the optical absorption cross section given by the following expression:

(2)

where is the oscillator strength, and is the Dirac delta function. The oscillator strength characterizing the rate of transitions between the initial, , and the final, , states is defined as Lee2002 ()

(3)

In Eq. (3) is the position operator and is the energy of a single-electron transition between the states with energies and . The summation in Eq. (2) is carried out over all possible transitions between the valence and conduction states.

To mimic thermal level broadening, finite single electron excitation lifetimes, nanocluster size inhomogeneity, etc., single electron absorption peaks in Eq. (2) are broadened by a Gaussian function with linewidth, ,

(4)

As follows from Eqs.(2) and (3), calculation of the absorption spectrum is reduced to a calculation of the matrix elements of the position operator, i.e., . Within the tight-binding model in its most general form this physical quantity is given by Leung1997 (); Leung1998 (); Schulz2006 ()

(5)

where is the position of the -th atom in the QD, is the atomic orbital of the -th atom, are the coefficients of the expansion of the electron wavefunction in terms of the atomic orbitals. The first sum in Eq. (5) is the dipole moment associated with the positions of the atoms of the QD. Due to the orthogonality of the electron wave functions of any two different states the value of this sum does not depend upon the choice of the origin of the coordinate system. Hence, only the relative atomic positions with respect to each other contribute to this term and, therefore, it is usually referred to as the inter-atomic dipole moment. The second sum of Eq. (5) represents the dipole moment of transitions between orbitals and located on the same atomic site and it is usually referred to as intra-atomic dipole moment. The intra-atomic dipole moment restores the result for an isolated atom in the limit of non-interacting atoms of the QD. In contrast to this, ZES arise due to the interaction between the atoms. Therefore, the contribution of intra-atomic dipole moments to the resulting dipole moment of transitions between low-energy states is assumed to be small. Taking into account the fact that the low-energy electronic structure of silicene and bilayer graphene QDs is formed by -atomic orbitals, one can reduce Eq. (5) to the following form:

(6)

where are the coefficients of expansion of the electron wave function in the basis of the -orbitals ,

(7)

The unknown coefficients of Eq. (7), , are the components of eigenvectors of the Hamiltonian given by Eq. (1).

(a)
(b)
(c)
Figure 3: Optical absorption cross sections of triangular (TRI) quantum dots with zigzag edges based on (a) graphene, (b) silicene and (c) bilayer graphene. Insets show zoomed in regions of interest. Each cluster has atoms per layer.

Iii Results and Discussion

iii.1 Optical absorption of triangular quantum dots

Optical absorption cross sections per atom, , were obtained in arbitrary units for graphene, silicene, and bilayer graphene clusters with atoms per layer ( Å for silicene and Å for single layer and bilayer graphene) by the procedure described in Section II. The results are depicted in Fig. 3. The number of ZES in the selected triangular clusters is equal to for graphene and silicene QDs, and to in the bilayer graphene QDs. This number can be expressed in terms of the size parameter , specified in Table 1, as and it should be multiplied by the number of layers for bilayer clusters. In the present calculations and thereafter the optical absorption cross section is a result of transitions from states below to states above the Fermi level. The linewidth for the main panels in Fig. 3 was selected to be equal to meV whereas, for the study of low-energy features (insets in Fig. 3), parameter was selected to be equal to meV for graphene and bilayer graphene, meV for silicene QDs.

We consider first transitions at zero electric field. The dependence of the optical absorption cross section for graphene clusters on the transition energy is shown in Fig. 3 (a). The results are in good agreement with those of Yamamoto et al. Yamamoto2006 () Figure 3 (b) presents the corresponding for silicene QDs. The low-energy zoom at the inset to this figure reveals the shift of the eV graphene peak towards eV in silicene as a result of the decrease in the hopping energy. The more important difference, however, is the splitting of this peak in two peaks. This effect is caused by the fact that ZES in silicene are no longer localized at  Hazem2 () and, therefore, the transition energy from the valence states to the ZES is different from the transition energy from the ZES to the conduction states.

The situation with the low-energy peak changes even more for the case of the triangular bilayer graphene QD where the ZES are smeared into the narrow energy band by the inter-layer electron hopping.Hazem2 () This smearing creates the dispersion of the optical absorption peaks in the region eV as shown in the inset of Fig. 3 (c). These peaks correspond to the possible transitions from the dispersed ZES and valance states to the dispersed ZES in the conduction band. Such a feature exists neither in graphene nor in silicene single layers where all the ZES are degenerate.

iii.2 Electric field effect and optical absorption

iii.2.1 Silicene QDs with zigzag edges

Figure 4 illustrates the effect of the electric field, , on the optical absorption (a), (c), (e) and on the energy levels spectrum (b), (d), (f) of triangular silicene QDs. As can be seen from Fig. 4(a), there is only one absorption peak below the energy eV when . This peak includes two types of transitions: from the highest occupied energy level (HOEL) to the ZES and from the ZES to the lowest unoccupied energy level (LUEL). In graphene these two types of transitions have the same transition energy but in silicene they are not identical and the energy difference between them, which is zero at , can be tuned by the electric field.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 4: Optical absorption cross sections (a), (c), (e) and corresponding energy levels (b), (d), (f) for a triangular zigzag silicene QD consisting of atoms ( Å) at different electric fields.

With increasing electric field two remarkable effects occur. Firstly, the two indicated transitions become non-identical, which results in splitting the corresponding peak in two peaks. The first peak lies below eV at V/Å, the first green peak in Fig. 4(c), while the second peak is positioned at the higher energy. Secondly, ZES become closer to the valence band states. Therefore transitions from some of the valence band states to ZES appear at the energies below eV. These transitions are represented by the second green peak in Fig. 4(c). In the higher field, V/Å, the energy difference between ZES and valence band states becomes even smaller which results in the appearance of the third green peak in Fig. 4(c). For a negative electric field the behaviour is similar but one should note that the absorption peaks at eV are now a result of transitions from ZES to the conduction band states.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 5: The same as Fig. 4, but for a hexagonal (HEX) silicene QD containing atoms ( Å) at different electric fields.

Hexagonal silicene QDs have no ZES. Therefore, the effect of the electric field is just in the opening of a tunable energy gap.Hazem2 () This is clearly seen in the optical absorption spectra as a shift of the edge of the absorption in Fig. 5(a), (c), (e). Without the electric field the absorption peaks are distributed almost uniformly in the region of eV. However, application of the field results in their shifting to the higher energies and in the emergence of an energy region with zero absorption. Thus, one can distinguish two regions with zero and non-zero absorption. Note also that the intensity of the peak near the absorption edge depends on the field. The increase of the electric field from to  V/Å results in a gentle decrease of the peak.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 6: Optical absorption spectra for armchair silicene QDs of triangular (a), (c), (e) and hexagonal (b), (d), (f) shapes, consisting of and atoms and having edge length  Å and  Å, respectively.

iii.2.2 Silicene QDs with armchair edges

In order to present the effect of edge termination on the electronic and optical properties of the silicene we extend our calculations to account for silicene flakes with armchair edges. The optical absorption cross sections of triangular and hexagonal silicene QDs with armchair edges are shown in Fig. 6. The total numbers of atoms are: and atoms ( Å and Å ) for triangular and hexagonal flakes, respectively. At zero electric field, see Fig. 6(a), the absorption spectrum for triangular armchair looks similar to the spectrum of triangular zigzag, see Fig. 4(a), with one absorption peak around eV. However, applying an electric field to triangular armchair clusters does not shift the absorption edge to the lower energy as in zigzag clusters. It is clearly seen in Fig. 6(a), (c), and (e) that the absorption edge blue shifts with the application of an electric field. The reason for such a behaviour is the absence of ZES in armchair silicene flakes. The shifting of the ZES in zigzag flakes closer to the conduction band or to the valance band decreases the energy gap. Unlike zigzag hexagonal QDs, armchair haexagonal clusters at have a significant energy gap eV. As indicated by Fig. 6(b), (d), and (f), in an electric field this gap increases similar to that opened by the field in the zigzag clusters.

iii.2.3 Bilayer graphene QDs with zigzag edges

In this section the clusters of triangular and hexagonal bilayer graphene QDs with number of atoms per layer and , respectively, are considered. We study the optical properties of the triangular bilayer graphene QDs, whose energy levels are shown in Fig. 7(b).

(a)

(b)
(c)

(d)
(e)

(f)
Figure 7: Optical absorption spectra (a), (c), (e) and energy levels (b), (d), (f) of a triangular bilayer graphene QD made of atoms per layer ( Å) at different electric fields. The insets show zoomed in absorption peaks below eV.

At zero field, ZES can be divided into two groups. The first group represents ZES located below the Fermi level, left side of the red line in Fig. 7(b), at eV. The second group represents ZES located above the Fermi level at eV. Then we study the optical absorption peaks resulting from the transitions between these two groups under the effect of electric field. In general, the smearing of ZES and the application of an electric field affects all optical transitions from and to ZES but we focus here only on the transitions between the two previously discussed groups of ZES. These transitions can be seen in Fig. 7(a) in the energy range from to eV. Thus, one can identify one group of optical transitions within the ZES. The inset of Fig. 7 (a) at V/Å shows a series of absorption peaks in the energy range from to eV. These small intensity peaks represent the group of transitions mentioned. The application of the electric field increases the tiny energy gap in the middle of the ZES band and gathers the ZES groups into the narrower energy range.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 8: The same as Fig. 7, but for a hexagonal bilayer graphene QD containing atoms per layer ( Å) at different electric fields.

This leads to the up-shift of the set of the low-energy absorption peaks to eV (for V/Å ) with the gathering of the small intensity peaks and increase in the peak intensity as shown in the insets of Fig. 7(c) at V/Å. Increasing the electric field to V/Å results in a further increase in the energy gap which in turn increases the intensity and the up-shift of the absorption peak to eV as can be seen in the inset of Fig. 7(e).

The optical absorption cross section and energy levels for a hexagonal bilayer graphene QD at different values of the electric field are shown in Fig. 8(a), (c), (e) and Fig. 8(b), (d), (f), respectively. In deep contrast to triangular bilayer graphene QDs, the energy gap in hexagonal bilayer graphene between the HOEL and LUEL, which is presented in Fig. 8(b) at E=0 V/Å, decreases with increasing electric field. This feature causes the shifting of some of the absorption peaks marked by green in Fig. 8(c), (e) to a lower energy and into the energy gap region. At V/Å two low-energy absorption peaks appear in the energy gap region at eV. Increasing to V/Å leads to further shifting of the absorption peaks to lower energy eV. Therefore, in small clusters we have blue/red shift for the low-energy absorption peaks for triangular/hexagonal bilayer graphene QDs.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 9: Energy gap dependence on the applied electric field in triangular (a)  Å, (c)  Å, (e)  Å and hexagonal (b)  Å, (d)  Å, (f)  Å bilayer graphene QDs.

In order to test this feature for different sizes of triangular and hexagonal bilayer graphene QDs we plotted Fig. 9, which illustrates the variation in energy gap upon application of electric field in clusters of different sizes. It can be seen from Fig. 9(b), (d), (f) that the energy gap in hexagonal clusters decreases with the application of electric field for small clusters and starts to increase with the field for a cluster size, where the total number of atoms is per layer. The energy gap for triangular clusters increases with the field for all the selected sizes as seen from Fig. 9(a), (c), (e).

We can differentiate two energy gaps. Fhe first one is the size dependent (size-energy gap) shown in Fig. 7(b) and the second is the stacking induced energy gap which occurs between ZES (ZES-energy gap) as indicated in Fig. 7(f). Due to the coupling parameters and the on-site potential in bilayer graphene, the ZES states split into two groups giving rise to the ZES-energy gap which is directly proportional to the applied electric field. If we consider the size-energy gap, shown in Fig. 7(b), we can easily see from Fig. 7(b), (d), and (f) that this energy gap decreases by increasing the electric field. Therefore the decreased energy gap as a function of electric field in HEX bilayer small QDs (Fig. 9(b), (d)) can be attributed to the absence of ZES in small clusters of HEX graphene bilayer QDs. Thus, there is only the size-energy gap which decreases in a similar manner to TRI bilayer graphene QDs. As shown in Fig. 9(f) increasing the size of the HEX cluster leads to oscillation of the energy gap as a function of the electric field. In fact, the oscillatory behaviour of the energy gap with electric field occurs not only for cluster with and higher but also for smaller clusters at higher values of the electric field. It has been reported recently that hexagonal bilayer graphene QDs with zigzag edges in the presence of an electric field exhibit unusual edge states inside the energy gap; these states oscillates as the applied electric field increases. Costa2015 () Therefore, according to the previous resultsCosta2015 () and our results, we conclude that the energy gap oscillation is a result of the oscillation of the edge states inside the gap due to increasing the electric field.

iii.2.4 Bilayer graphene QDs with armchair edges

As discussed above for zigzag bilayer clusters, the increase (decrease) in the absorption gap can be obtained through applying an electric field to triangular (hexagonal) bilayer graphene QDs. Bilayer graphene QDs with armchair termination do not support edge states, thus it is expected that armchair triangular and hexagonal bilayer QDs will follow a similar trend to that obtained in hexagonal zigzag QDs. Figure 10 illustrates the optical absorption cross section of triangular [Fig. 10 (a), (c), (e)] and hexagonal [Fig. 10 (b), (d), (f)] bilayer graphene QDs at different values of electric field. We notice that for triangular and hexagonal clusters at E=0 V/Å there are two absorption peaks in the energy range from to  eV. Application of an electric field leads to increase in the number of absorption peaks in this energy region and a small shift to lower energy.

(a)

(b)
(c)

(d)
(e)

(f)
Figure 10: Optical absorption spectra for armchair bilayer graphene QDs of triangular (a), (c), (e) and hexagonal (b), (d), (f) shapes with ( Å) and ( Å) atoms per layer, respectively.

Iv Conclusions

The optical absorption spectra of silicene and bilayer graphene QDs have been investigated for triangular and hexagonal clusters and compared to the corresponding clusters of monolayer graphene. Silicene QDs in a zero electric field show two optical transition peaks from HOEL in the valence band to ZES and from ZES to the LUEL in the conduction band. In contrast to this in graphene QDs these two optical transitions are identical and produce one absorption peak because HOEL and LUEL are symmetric with respect to the ZES. In general, doubling the number of transition peaks occurs not only for transitions from HOEL to ZES and from ZES to LUEL but also for all transitions from all valence band energy states to ZES and from ZES to all conduction band states. Without the electric field, triangular bilayer graphene QDs exhibit optical transitions between the ZES themselves due to the smearing of their ZES. These transitions do not exist in graphene or silicene QDs.

The introduction of an electric field into silicene triangular QDs displaces the ZES in the energy gap such that they are closer to the conduction states in the case of a positive electric field and push them further away for a negative field. This displacement increases with increasing electric field, thereby increasing the number of absorption peaks in the low-energy region of the optical absorption spectrum. By contrast, hexagonal silicene QDs show a reduction in the number of optical absorption peaks in the low-energy region with increasing electric field in either direction. In triangular bilayer graphene QDs the small energy gap between the ZES increases with increasing electric field. As a result of these field-dependent energy gaps, the edge of absorption due to transitions between ZES undergoes blue shift in response to the applied field. For small clusters of hexagonal bilayer graphene, the edge of absorption has a red shift with increasing electric field.

Armchair flakes of silicene and bilayer graphene exhibit a significant dependence of their optical properties with electric field. The blue (red) shift of the absorption edge takes place for silicene (bilayer graphene) flakes for both hexagonal and triangular shapes. The absence of ZES in armchair flakes removes the ability to switch the trend of energy gap dependence on the electric field by changing the shape between triangular and hexagonal. Therefore ZES provide a privilege in silicene and bilayer graphene QDs with zigzag edges over those with armchair edges in controlling the electronic and optical properties using different shapes.

The results of the present study should be supplemented in the future by more sophisticated models which take into account electron-electron interaction. For instance, the low-energy absorption of the bilayer clusters in conjunction with the magnetic phase transition Guclu2011 (), depending on the value of the applied electric field, is worth special attention since in this case electron-electron interaction may results in emergence of additional low-energy transitions. However, we expect that this will not change much the revealed general trends. For instance, electron-electron interaction should not drastically affect such reported features as the highly tunable absorption peak centered at about eV for zigzag silicene QDs of triangular shape. The on-site Coulomb repulsion, omitted in the present consideration, should increase the splitting of the peaks caused by the spin-orbit term in silicene and parameters and in the bilayer graphene QDs for transitions between ZES and the valence (conduction) band states.

Thus, we have shown that optical spectroscopy in an applied electric field provides a powerful tool for determining the shape and size of the small clusters of silicene and bilayer graphene. In addition, our results provide the basis for using small silicene and bilayer graphene clusters as active elements of mid-infrared optoelectronic devices tunable by an external electric field.

Acknowledgements.
This work was supported by the EU FP7 ITN NOTEDEV (Grant No. FP7-607521); EU H2020 RISE project CoExAN (Grant No. H2020-644076); FP7 IRSES projects CANTOR (Grant No. FP7-612285), QOCaN (Grant No FP7-316432), InterNoM (Grant No FP7-612624); Graphene Flagship (Grant No. 604391) and the Egyptian mission sector. The authors are thankful to Dr. C. A. Downing from IPCMS for helpful discussions and hospitality in Strasbourg and R. Keens for a careful reading of the manuscript.

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