Charge Transport in Weyl Semimetals

Charge Transport in Weyl Semimetals

Pavan Hosur Department of Physics, University of California at Berkeley, Berkeley, CA 94720    S. A. Parameswaran Department of Physics, University of California at Berkeley, Berkeley, CA 94720    Ashvin Vishwanath Department of Physics, University of California at Berkeley, Berkeley, CA 94720 Materials Science Division, Lawrence Berkeley National Laboratories, Berkeley, CA 94720
Abstract

We study transport in three dimensional Weyl semimetals with isotropic Weyl nodes in the presence of Coulomb interactions or disorder at temperature . In the interacting clean limit, we determine the conductivity by solving a quantum Boltzmann equation within a ‘leading log’ approximation and find it to be proportional to , upto logarithmic factors arising from the flow of couplings. In the noninteracting disordered case, we compute the finite-frequency Kubo conductivity and show that it exhibits distinct behaviors for and : in the former regime we recover the results of a previous analysis, of a finite conductivity and a Drude width that vanishes as ; in the latter, we find a conductivity that vanishes linearly with whose leading contribution as is the same as that of the clean, non-interacting system . We compare our results to experimental data on YIrO and also comment on the possible relevance to recent transport data on EuIrO.

There has been a surge of recent activity studying Dirac excitations in two dimensional media, most famously graphene Geim and Novoselov (2007). A natural question is whether there are analogs in three dimensions, with a vanishing density of states at the chemical potential and linearly dispersing excitations. It has long been known that touchings between a pair of non-degenerate bands are stable in three dimensions, and typically have linear dispersion. Near these, electronic excitations are described by an analog of the Weyl equation of particle physics, which describes two-component chiral fermions Herring (1937); Abrikosov and Beneslavskii (1971); Nielsen and Ninomiya (1983). Hence these states have been dubbed Weyl semi-metals (WSMs) Wan et al. (2011).

To remove a band touching (or Weyl node) one necessarily must connect to another node. This is in contrast with two dimensions: graphene’s nodes can be gapped by different intranode perturbations that break inversion () or time reversal () symmetry. The enhanced protection in three dimensions is due to a topological property of the nodes - they are sources (monopoles) of Chern flux in the Brillouin zone (BZ). This momentum space topology is associated with several physical phenomena. In particular, it was recently realized Wan et al. (2011) that unusual surface states will result as a consequence of the band topology. These take the form of Fermi arcs that connect the projections of the nodes onto the surface BZ. Such topological properties are sharply defined as long as one can distinguish band touching associated with opposite Chern flux. The presence of translation symmetry, and hence conserved crystal momenta, is sufficient to protect these defining properties since the nodes are separated in the BZ. In principle one needs perfect crystalline order to define these phases; in practice, smooth disorder that only weakly mixes nodes is expected to have little effect. Other manifestations of the band topology include an anomalous Hall effect Yang et al. (2011); Burkov and Balents (2011) that is tied to the momentum space displacement between nodes, and magneto-resistance arising from Adler-Bell-Jackiw anomaly of Weyl fermions Aji (2011); Nielsen and Ninomiya (1983).

Physical realizations of WSMs require non-degenerate bands to touch; therefore spin degeneracy must be lifted (by either spin-orbit interactions or magnetic order), and either or must be broken: otherwise, all bands would be doubly degenerate. We further require that the Fermi ‘surface’ consists exactly of the Weyl nodes. In -breaking realizations where is unbroken, a simple ‘parity criterion’ applied to eight -invariant momenta in the BZ can be used to diagnose the existence of Weyl nodes Turner et al. (2010). In Wan et al. (2011), certain pyrochlore iridates AIrO (AY or Eu), were proposed to be magnetically ordered WSMs, with Weyl points, all at the Fermi energy; Witczak-Krempa and Kim (2011) reached similar conclusions but with . Alternate proposals include HgCrSe in the ferromagnetic state Xu et al. (2011) and topological insulator-ferromagnet heterostructures Burkov and Balents (2011), with , the minimum allowed.

Motivated by the availability of transport data on the iridates Yanagishima and Maeno (2001); Tafti et al. (2011), we study the electrical conductivity of an idealized model of a WSM, with an even number of isotropic Weyl nodes characterized by the same dispersion, with nodes of each chirality as required by topology Nielsen and Ninomiya (1981); Wan et al. (2011). In the absence of impurities and interactions we expect the free fermion result, . We demonstrate how this is modified in two cases:

(i) in clean undoped systems with Coulomb interactions, current is carried equally by counterpropagating electrons and holes and can be relaxed via interactions alone. Solving a quantum Boltzmann equation (QBE) we find a finite conductivity proportional to the temperature (upto logarithmic factors), as expected of a quantum critical system Fritz et al. (2008), where is the sole energy scale,

(1)

Here and are the Fermi velocity and fine structure constant renormalized to the scale of the temperature , and and are the corresponding ‘bare’ values at the microscopic scale (See App. B).

(ii) In the presence of impurities, power counting shows that white-noise disorder is an irrelevant perturbation, and a naive expectation is that the clean result is reproduced. However, the result is more interesting: by evaluating a standard Kubo formula, we find that the the finite-frequency conductivity exhibits different behaviors for and : in the former regime we find in agreement with Burkov and Balents (2011) a finite Drude-like response with a peak width vanishing as ; in the latter, we recover as the leading behavior, which is universal and independent of disorder. We also determine the manner in which the conductivity interpolates between these limits.

Previous studies of 3D Dirac points have assumed Lorentz invariance Arnold et al. (2003) or worked at a topological phase transition between insulators Goswami and Chakravarty (2011). Although our work differs from both of these situations – instantaneous Coulomb interactions break Lorentz invariance, and we study a stable phase – there are sufficient parallels that a similar ‘leading log’ approximation suffices to solve the QBE. Coulomb interactions also lead to a finite dc conductivity in clean graphene – the 2D analog of a WSM – but the leading log approximation fails here and more analysis is needed Fritz et al. (2008); Kashuba (2008).

The Model.- In a WSM, the electronic dispersion about a Weyl node is generically of the form , where are the Pauli matrices. The velocities satisfy , and the Chern number (‘chirality’) associated with the Weyl node is . For simplicity, we shall drop the term proportional to identity and assume isotropic dispersion; relaxing this assumption should only produce small corrections. The Hamiltonian for a system of identically dispersing Weyl nodes (‘flavors’) with Coulomb interactions and disorder may then be written as , with (repeated indices summed)

(2)

where is a two-component spinor in the (pseudo)spin indices , index the flavors, is the Fermi velocity, which we set to unity, is the chirality of the Weyl node, describes the Coulomb interaction in a material with dielectric constant , is a random potential with white-noise correlations where characterizes the strength of the individual impurities and their concentration, , and we have written assuming that the Fermi level is at the Weyl nodes, which is the only case studied in this Letter. Here and below we set , and define .

Conductivity with Interactions.- Critical systems – such as graphene and the WSM at neutrality– are exceptions to the rule that disorder is essential for a finite conductivity, since they support current-carrying states in which particles and holes transport charge with no net momentum by moving exactly opposite to each other. In contrast to conventional finite-momentum charge transport, such deviations from equilibrium can relax in the presence of interactions alone, leading to a finite conductivity.

We study transport in an interacting WSM by solving a QBE for the thermal distribution function of quasiparticle states. In doing so, it is convenient to first calculate the current from a single node (but interacting with all the nodes), before making the leap to the current carried by all nodes. We focus on a node with flavor , which we take to have . The single-quasiparticle states are obtained by diagonalizing : , , and are labeled by their helicity (the eigenvalue of .) From now on we will suppress the index . In general, operators corresponding to various transport properties are not diagonal in the helicity; diagonal contributions correspond to motion of particles and holes in the applied field and may be characterized by appropriate distribution functions , while the off-diagonal terms () describe the motion of particle-hole pairs, which are finite-energy states. At particle-hole symmetry and for , contributions of the latter to transport are expected to be small, and we drop them forthwith. In this approximation, it is therefore sufficient to solve the QBE for quasiparticle distribution functions , subject to an external force ,

(3)

where is the rate at which quasiparticles scatter out of the state at time , and captures the effect of interactions. Our goal will be to determine the steady-state form of the non-equilibrium quasiparticle distribution function. We will restrict ourselves to linear response in , i.e. we assume that the deviation of from equilibrium is small. The result is a linear functional equation which may be recast as a variational problem. We solve the latter approximately by identifying ‘leading log’ contributions, which dominate the relaxation of the observable under consideration. As mentioned, we assume that the constants that enter the solution of (3) are renormalized to the energy scale of interest, namely .

Neglecting particle-hole pair contributions, the current is . For a weak applied electric field , the deviation of from the equilibrium distribution function , and hence the conductivity , can be parametrized 111We have used the fact that at particle-hole symmetry, the deviation from equilibrium is proportional to the sign of , and . in terms of a dimensionless, isotropic function :

(4)
(5)

It therefore remains only to determine the function , to which we now turn. Inserting (4) into (3), and working to linear order in , we find where is the collision operator, a linear functional of given in A. This is equivalent to the variational problem of extremizing the quadratic functional Goswami and Chakravarty (2011); Kashuba (2008); Fritz et al. (2008); Arnold et al. (2003)

in which we have rescaled all momenta and frequencies by . A key simplification, known as the ‘leading log’ approximation (LLA) stems from the power-law nature of the Coulomb interaction: as a result of this, logarithmically divergent small-momentum scattering dominates . We may write , which when thought of as linear functionals of have eigenvalues of and , respectively. In the LLA we approximately optimize by choosing in the space spanned by eigenstates of ; as shown in App. A the choice yields

(7)

optimized by Finally, we observe that the flipped chirality of half the nodes is unimportant as they all give the same contribution to ; thus using the result for in (5) and multiplying by we find the result for nodes 222As mentioned in the introduction, and take on their renormalized values at temperature ,

(8)

Note that in the case of graphene, the LLA fails because the log divergence stems from a phase space effect due to enhanced scattering of collinear particles, which cannot relax a current. Thus, the eigenstates of do not contribute to the relaxation, which therefore occurs only via subleading, noncollinear scattering, i.e. Fritz et al. (2008); Kashuba (2008). In 3D, includes noncollinear and thus current-relaxing processes, so that the LLA analysis is sufficient Arnold et al. (2003); Goswami and Chakravarty (2011).

In the dc limit, (8) reduces to (1), which we may rationalize in terms of the relaxation time approximation to the QBE. Here, we take , and use a combination of dimensional analysis and a straightforward application of Fermi’s golden rule to estimate the scattering rate as . From this, we find the conductivity to be similar to (1), modulo logarithms. This provides an estimate of the frequencies over which transport is collision-dominated and the preceding calculation is valid: in order for collisions to produce relaxation, we require , which occurs for .

Conductivity with impurities.- We turn now to the conductivity of the noninteracting, disordered system. We restrict to the case of scattering off random point impurities, characterized by and the locations of which we shall assume are uncorrelated, . With these assumptions, we are led to in (2) with . As before, we first compute the conductivity for a single node. Assuming that the impurities are sufficiently dilute that the Born approximation is valid, the quasiparticle lifetime due to impurity scattering from a single node is given by where is the retarded self-energy, is the Green’s function for a noninteracting Weyl fermion with helicity , and the form factor from the overlap of helicity eigenspinors, to leading order. We find (see App. C.1) , where is the density of states and characterizes the strength of the impurity potential.

To evaluate the conductivity we use the Kubo formula,

(9)

where is the retarded response function which for a system of linear dimension is defined to be

(10)

with , and . From gauge invariance , so that (suppressing ), . Some algebra yields (see App. C.2)

where is the Fermi-Dirac function and we have used the retarded helicity-basis Green’s function dressed with disorder lines, . After a tedious calculation, we may write where , , so that , is a characteristic scale set by the disorder strength, and with a complicated rational function shown in App. C.2.

In our model disorder can scatter between nodes, so acquires a factor of when ; in common with the interacting case, also has an overall prefactor of . From these it is easy to show that for nodes,

(12)

which is identical to the result (Fig. 1) upon rescaling .

Figure 1: Frequency-dependent conductivity of a single Weyl node with disorder (constants defined in the text.)

While in general we integrate (12) numerically, in certain limits an analytic treatment is feasible. For , . Expanding in powers of and resumming only terms dominant as , we recover the result of Burkov and Balents (Eq. (15) of Burkov and Balents (2011)): namely, a Drude-like response with a width vanishing as , and a finite dc limit of .

In the opposite limit, at finite we may replace the Fermi functions by step functions, which yields

(13)

The leading term is universal and independent of disorder, and is simply . Both regimes are captured in Fig. 1, which shows for , beyond which the Born approximation is insufficient.

Figure 2: and (defined in the text) for the inset parameter values compared to experimental data from Yanagishima and Maeno (2001).

Experiments.- In Yanagishima and Maeno (2001) the dc resistivity of polycrystalline YIrO was found to vary with temperature as over , which is reminiscent of our result with interactions (1). Accordingly, we compare this data with a model of a clean WSM with Wan et al. (2011), as shown in Fig. 2. We find rather good agreement with experimental data for physically reasonable parameter choices, shown inset. Very recently, transport in single crystals of another pyrochlore iridate, EuIrO, has been studied Tafti et al. (2011) under pressure for ; at low pressures, resembles Fig. 2, consistent with WSM behavior.

Conclusions.- The conductivity of WSMs thus exhibits a rich variety of behavior on varying frequency and temperature, in both the interacting clean and noninteracting disordered limits, as shown in Figs. 1 and 2. In particular, its nontrivial dependence on is sensitive to the strength of the interactions; with just disorder, we find a striking difference between the and regimes, with the ac response dominated by a universal, disorder-independent contribution. While the limited existing dc conductivity data on the candidate iridates broadly agrees with our theory in the clean limit, we caution that more dc and ac conductivity measurements on single crystals with controlled disorder are required to make a rigorous comparison. Theoretically, the interplay of disorder and interactions, and corrections to the isotropic node approximation still need to be considered. In particular, it would be striking if the distinct behavior of the disordered system across the different frequency regimes survives the inclusion of interactions; these questions we leave open for the future.

We thank P. Goswami, L. Fritz, S.L. Sondhi, S. Ryu and A. Turner for discussions, and acknowledge funding from the Simons Foundation (SAP) and the Laboratory Directed Research and Development Program of LBNL under US DOE Contract DE-AC02-05CH11231 (AV).

Appendix A The Collision Operator and the ‘Leading Log’ Approximation

In order to define the collision operator , introduced in the main text, we need to determine the tree-level scattering amplitudes due to the interaction and how they couple the quasiparticle distributions at different momenta. An additional complication stems from the fact that of the Weyl nodes, have chirality . It is easily verified that the single-particle dispersion of the Weyl node is given by , so that for the eigenspinors of with eigenvalues are interchanged relative to . For convenience, we define , so that the energy is with . As the Coulomb interaction is instantaneous, the collision operator is diagonal in frequency. is then given by

(14)

where

(15)

is the scattering amplitude for two-particle scattering from to and in addition depends on the chiralities of the initial and final nodes. This dependence comes from the fact that the scattering amplitude depends explicitly on the overlap of the initial and final spinors, which in the -representation introduced above depends on their chiralities. We observe here that in the limit (which, as we will shortly see, dominates the current relaxation) , corresponding to the fact that scattering is indifferent to the chirality, so the fact that half the Weyl nodes have a chirality opposing the one under consideration is unimportant.

Using Fermi’s golden rule, it is now straightforward to show that the collision operator is

(16)

where

(17)

and

(18)

describe scattering between oppositely and identically charged particles, respectively. The diagrams corresponding to scattering processes are the same as in Ref. Fritz et al., 2008.

Turning now to the -dependent portion of the expression for the functional , we may use the symmetries of under combinatorial exchanges of momenta to write (in rescaled variables ) the first term in as

(19)

We now specialize to a perturbation of the form , which is a zero mode of the processes. This leaves only the terms in (A) proportional to . We may represent the energy-conserving -function as

Next, we choose coordinates in which is along so that

and similarly for . The angular integrals over and can now be done trivially, at the cost of leaving a complicated dependence on in , . For , the and integrals give one if and 0 otherwise; we will show that it suffices to consider small , so the knowledge of this regime is sufficient. With these observations, we have

(20)

The cross-helicity scattering rate contains terms of the form , which diverge as at small for direct scattering; the exchange contributions remain finite and do not contribute at leading order. The integral over the dummy variable gives one power of in thenumerator and substitution of our ansatz shows that the term in braces gives two more powers of , so that at small , the integrand is proportional to , which gives a logarithmic divergence. It is this logarithmically dominant contribution that is referred to in the text as , whence we implicitly define .

Having identified the dominant contribution to the collision integral, we proceed as follows: first, we substitute our ansatz into the expression above, and perform the integral over ; as this integral is logarithmically divergent in both the UV and the IR, we will need to regulate it appropriately. The UV cutoff is the temperature , as this is the largest physical energy scale in the problem; in the IR, the divergence is avoided due to thermal screening of the Coulomb interaction which occurs at an energy scale set by both the coupling constant and the temperature, which we take to be . With these choices, we may perform the integral over , and then set in the remainder, leaving integrals over , and which may then be performed straightforwardly; upon including the parts of the functional that are independent of the collision operator, we arrive at the results quoted in the text for the LLA.

Appendix B Renormalization of couplings

Figure 3: One-loop diagrams that govern the flow of the marginal couplings and .

As mentioned in the text, in order to make a meaningful comparision between the calculated conductivity and experimental data at temperature , we need to use values of the various parameters renormalized to the characteristic energy scale . In order to determine these, we work with the Euclidean path integral , written in terms of the gauge-fixed action

(21)

which (as is easily verified) is equivalent to the Hamiltonian described earlier. Here, is a static external vector potential, while is a dynamical field that mediates the instantaneous Coulomb interaction between the electrons. We implement a momentum-space cutoff , but leave the frequencies unrestricted so that the interaction always remains instantaneous; we then study the flow of as we lower . The action has three dimensionless parameters – the Fermi velocity , the electric charge and the dielectric constant – all of which are unrenormalized, and hence marginal, at tree level. Of these, is further protected against renormalization to all orders in perturbation theory by gauge invariance. However, and have no such protection and at one loop they acquire corrections of when is lowered to . The diagrams governing the flow of and at this order in are the one-loop self-energy and the fermion (RPA) bubble (see Fig. 3) diagrams respectively; performing the sum over flavors where appropriate, we find that the corrections are, respectively, independent of and proportional to . Evaluation of the corresponding integrals leads to the flow equations

(22)

where is the usual RG scale parameter. Integrating (22) between an upper cutoff (which we leave unspecified for the time being, but will take to be much higher than any scale relevant to transport measurements, but lower than the energy at which band curvature corrections become significant) and the temperature scale, gives the renormalized parameters used in the text. These renormalized values of and are to be used in the formula for [Eq.(1) of the main text] to compute the conductivity at temperature , while retains its bare value due to gauge invariance. Representative results are shown in Fig. 5.

We remark on an important distinction between the case of the Weyl semimetal in and its two-dimensional analog, graphene. In the case of graphene, while the electrons are restricted to two dimensions, their interaction continues to be of the form since the electromagnetic field lines are not thus constrained; in momentum space, this leads to a non-analytic form for the instantaneous interaction, . Since the RG procedure outlined above can only produce analytic corrections at any order, thus remains unrenormalized. In , we have an analytic , and so can and does receive corrections at one loop and beyond.

Figure 4: Resistivity as a function of temperature for -node Weyl semimetals with and .
Figure 5: Renormalized fine-structure constant as a function of temperature for -node Weyl semimetals with and .
Figure 4: Resistivity as a function of temperature for -node Weyl semimetals with and .

Appendix C Conductivity with Disorder

c.1 Scattering Time

The scattering time is given in terms of the imaginary part of the retarded self-energy by, where

(23)

with all quantities defined as in the text. Imposing a cutoff , performing the angular integration, and rewriting the negative-helicity Green’s function by changing variables we have

(24)

independent of , whence , where is the density of states and . Note that is formally divergent with the cutoff regularization used here; however this can be absorbed into a renormalization of and we shall not discuss it further.

c.2 Evaluation of the Kubo Response

In order to evaluate the conductivity we require the retarded response function which is obtained most simply by working in the Matsubara formalism and analytically continuing the results to real frequency. The leading contribution to the Matsubara response function corresponds to the particle-hole bubble with impurity-dressed propagators, and in terms of Matsubara Green’s functions in the pseudospin basis takes the form

(25)

where and the trace is over the pseudospin indices. Performing this trace and summing over the spatial index , we obtain

where